75898-60-1

Basic information

• Product Name: benzyloxycarbonyl-γ-benzyl-α-L-glutamyl-D-glutamine
• CAS NO: 75898-60-1
• Molecular Weight: 499.521
• Mol File: 75898-60-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyloxycarbonyl-γ-benzyl-α-L-glutamyl-D-glutamine(CAS DataBase Reference)
• NIST Chemistry Reference: benzyloxycarbonyl-γ-benzyl-α-L-glutamyl-D-glutamine(75898-60-1)
• EPA Substance Registry System: benzyloxycarbonyl-γ-benzyl-α-L-glutamyl-D-glutamine(75898-60-1)

Safety Data

• Hazardous Substances Data: 75898-60-1(Hazardous Substances Data)

Upstream product

• 5680-86-4 N-benzyloxycarbonyl-5-O-benzyl-L-glutamic acid 
• 5959-95-5 D-Glutamin 
• 67413-34-7 O^γ-benzyl-N^α-benzyloxycarbonylglutamic acid succinimidyl ester 

Relevant articles and documents

Synthesis of γ-Glutamyl Peptides Catalyzed by Transamidase from Bacillus natto

Crude ammonium sulfate fraction of a cell free extract from Bacillus natto contained an enzyme (or enzymes) which catalyzed the transamidation reaction specific for glutamine.Both L- and D-isomers of glutamine were active as substrate.On incubation of L- or D-glutamine with the enzyme preparation, two peptides consisting of glutamic acid and glutamine were formed.The main component of the peptides was readily isolated by ion-exchange chromatography and identified as γ-glutamylglutamine by paper chromatography and by paper electrophoresis using authentic peptides.The optical configuration of the amino acid residues in the dipeptide was determined by digestion of the acid hydrolyzate with L-glutamic acid decarboxylase, and the result showed that the dipeptide obtained from L-glutamine was a L-L isomer, while the dipeptide from D-glutamine was a D-D isomer.