759-02-4

Basic information

• Product Name: 2,4-Pentanedione, 3-fluoro- (6CI,8CI,9CI)
• Synonyms: 2,4-Pentanedione, 3-fluoro- (6CI,8CI,9CI)
• CAS NO: 759-02-4
• Molecular Formula: C₅H₇FO₂
• Molecular Weight: 118.1062832
• Product Categories: ACETYLGROUP
• Mol File: 759-02-4.mol
• Article Data: 16

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,4-Pentanedione, 3-fluoro- (6CI,8CI,9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Pentanedione, 3-fluoro- (6CI,8CI,9CI)(759-02-4)
• EPA Substance Registry System: 2,4-Pentanedione, 3-fluoro- (6CI,8CI,9CI)(759-02-4)

Safety Data

• Hazardous Substances Data: 759-02-4(Hazardous Substances Data)

Usage

General Description

2,4-Pentanedione, 3-fluoro- (6CI,8CI,9CI) is a chemical compound with the molecular formula C5H7FO. It is a fluoro-substituted derivative of 2,4-pentanedione, which is commonly used as a flavoring and fragrance ingredient. The 3-fluoro substitution alters the properties and potential uses of the compound, and it may have applications in pharmaceuticals, agrochemicals, and other industries. Its specific chemical and physical properties, as well as its potential hazards and uses, would need to be determined through further research and analysis.

Upstream product

• 430-51-3 1-fluoro-2-propanone 
• 108-24-7 acetic anhydride 
• 13257-81-3 4-trimethylsiloxy-3-penten-2-one 
• 123-54-6 acetylacetone 
• 1694-29-7 3-chloropentane-2,4-dione 

Downstream Products

• 144219-90-9 4-fluoro-3,5-dimethyl-1-phenyl-1H-pyrazole 
• 100818-58-4 ethyl 3,5-dimethyl-4-fluoropyrrole-2-carboxylate 
• 57160-76-6 4-fluoro-3,5-dimethyl-1H-pyrazole 
• 1414859-56-5 3,5-diphenyl-6-fluoro-6-acetyl-2-enecyclohexanone 
• 1414859-57-6 3-(4′-methoxyphenyl)-5-phenyl-6-fluoro-6-acetyl-2-enecyclohexanone 
• 1414859-58-7 3-styryl-5-phenyl-6-fluoro-6-acetyl-2-ene-cyclohexanone 
• 1403591-20-7 5-chloro-3-{ethyl[(1r,4r)-4-(dimethylamino)cyclohexyl]amino}-N-[(5-fluoro-4,6-dimethyl-2-oxo-1,2-dihydropyridin-3-yl)methyl]-2-methylbenzamide 

Relevant articles and documents

C-F Bond Activation of a Perfluorinated Ligand Leading to Nucleophilic Fluorination of an Organic Electrophile

We report a fluorine transfer reaction in which fluorine from a perfluorinated ligand undergoes C-F bond activation and transfers to an electrophile, resulting in the formation of a new fluorinated product and dimerization of the monodefluorinated complex. Treatment of [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)-RhCl] with the organic electrophile, toluoyl chloride, resulted in the formation of a rhodium(III) metallocycle via C-F bond activation assisted defluorinative coupling. Fission of the C-F bond liberated nucleophilic fluoride, which converted acyl chloride to acyl fluoride. The overall reaction was monitored using a multivariate analysis approach in real time.

One-pot fluorination and Mannich reactions of 1,3-dicarbonyl compounds

Abstract One-pot fluorination of 1,3-dicarbonyl compounds with Selectfluor followed by the Mannich reaction with anilines and benzaldehydes is developed for the synthesis of α-fluoro and aminomethylated 1,3-dicarbonyl compounds.

One-pot fluorination followed by Michael addition or Robinson annulation for preparation of α-fluorinated carbonyl compounds

Fluorination followed by the Michael addition or Robinson annulation of 1,3-dicarbonyl compounds is introduced for the synthesis of acyclic and cyclic α-fluoro-β-ketoesters and α-fluoro-1,3-diketones. The decarboxylation step can also be added to the reac