759-30-8

Basic information

• Product Name: Propanedioic acid, (1,2-dimethyl-2-propenyl)-, diethyl ester
• CAS NO: 759-30-8
• Molecular Formula: C12H20O4
• Molecular Weight: 228.288
• Mol File: 759-30-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, (1,2-dimethyl-2-propenyl)-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, (1,2-dimethyl-2-propenyl)-, diethyl ester(759-30-8)
• EPA Substance Registry System: Propanedioic acid, (1,2-dimethyl-2-propenyl)-, diethyl ester(759-30-8)

Safety Data

• Hazardous Substances Data: 759-30-8(Hazardous Substances Data)

Upstream product

• 105-53-3 diethyl malonate 
• 78-79-5 isoprene 
• 14309-15-0 phenyl prenyl ether 
• 50340-56-2 ethoxy-3 methyl-3 butene-1 
• 24509-88-4 2-methyl-3-buten-2-yl acetate 
• 40426-44-6 3-methoxy-3-methyl-1-butene 
• 22094-00-4 ether d'ethyle et de prenyle 
• 115-18-4 2-methyl-3-buten-2-ol 
• 996-82-7 sodium diethylmalonate 

Relevant articles and documents

Etude de l'allylation, catalysee par le nickel, d'enolates stables, par les ethers et les alcools allyliques

The allylation of stable enolates derived from diethyl malonate and ethyl cyanoacetate by a variety of aliphatic or aromatic allylic ethers and by allylic alcohols, under nickel catalysis, was investigated.The influence of ligands, solvents and temperature was studied.

ETUDE DE LA REGIOSELECTIVITE DE LA SUBSTITUTION DES CARBANIONS PAR DES DERIVATIVES ALLIQUES CATALYSEE AU PALLADIUM. OBTENTION SELECTIVE DE COMPOSES A CARBONE QUATERNAIRE

The influence of the leaving groups, carbanions and ligands on ?-allylpalladium has been investigated in the substitution of primary or tertiary terpene derivatives.Conditions have been found under which the substitution takes place essentially at one or the other end of the allylic system.This provides a new and convenient way to obtain compounds with quaternary carbon atoms, which has been exemplified by the synthesis of 3,3-dimethyl-4-pentenenitrile.