7608-19-7Relevant articles and documents
Br?nsted Base Mediated Stereoselective Diphosphination of Terminal Alkynes with Diphosphanes
Okugawa, Yuto,Hirano, Koji,Miura, Masahiro
, p. 2973 - 2976 (2017/06/07)
A Br?nsted base mediated stereoselective diphosphination of terminal alkynes with diphosphanes proceeds to deliver the corresponding (E)-1,2-diphosphinoethenes in good yields. The reaction of aromatic alkynes occurs efficiently in the presence of a catalytic amount of LiO-t-Bu while MN(TMS)2 (M = Li or Na) gave better results in the case of aliphatic substrates. The Br?nsted base mediated protocol can offer a good alternative to precedented transition-metal-catalyzed or radical-promoted approaches to the 1,2-diphosphinoethene framework of potent interest in catalysis and coordination chemistry.
REACTIONS OF PHOSPHORUS(III) THIO ESTERS WITH SUBSTITUTED 1-CHLOROACETYLENES. N,N,N',N'-TETRAALKYL-P-ETHYNYLPHOSPHONOTHIOIC DIAMIDES WITH ANTIVIRAL ACTIVITY
Sinyashin, O. G.,Zubanov, V. A.,Pozdeev, O. K.,Gil'manova, G. Kh.,Batyeva, E. S.,Pudovik, A. N.
, p. 1102 - 1108 (2007/10/02)
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