761408-46-2Relevant articles and documents
Poly(ε-caprolactone) macroligands with β-diketonate binding sites: Synthesis and coordination chemistry
Bender, Jessica L.,Shen, Qun-Dong,Fraser, Cassandra L.
, p. 7277 - 7285 (2007/10/03)
Dibenzoylmethane (dbm) initiators with one and two alcohol sites were used to generate dbm end-functionalized and dbm-centered poly(ε-caprolactone) macroligands (dbmPCL and dbmPCL2) with low polydispersities (~1.1). Chelation of polymeric ligands to metal ions (Eu3+, Fe3+, Ni2+ and Cu2+) produced metal-centered star polymers, which were characterized by UV-vis and fluorescence spectroscopy, as well as gel permeation chromatography.