7616-22-0Relevant articles and documents
Whistance,Threlfall
, p. 213,215 (1970)
FORMATION OF CHIRAL 4-CHROMANONES USING CHIRAL PYRROLIDINES IN THE PRESENCE OF ACIDS
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Page/Page column 32; 33, (2015/01/16)
The present invention relates to a synthesis of chromanones or chromanes in a stereospecific matter in view of the 2-position in the chromanone or chromane ring. It has been found that this synthesis is particularly possible in the presence of a chiral compound of a specific type and of at least one Bransted acid or in the presence a specific chiral compound having a Bransted acid functional group in the molecule.
Process for separating tocopherol homologues
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Page/Page column 2-3, (2008/06/13)
Methods for separating gamma and delta homologues of tocopherol are described.
Preparation of chromanyl derivatives
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, (2008/06/13)
A process for the preparation of chromanyl derivatives of the formula I STR1 where R1 is hydrogen, C1 -C8 -alkyl, aryl, aralkyl, Si(R4)3, C(=O)R4 or C1 -C4 -alkoxymethyl, R2 and R3 are hydrogen or C1 -C3 -alkyl, and R4 is C1 -C8 -alkyl or aryl, which comprises decarboxylating 5-carboxychromanyl derivatives of the formula II STR2 where the substituents R1 to R3 are as defined above and 5-carboxylchromanyl derivatives of the formula II.