76238-22-7

Basic information

• Product Name: ACETIC ACID CIS-6-NONEN-1-YL ESTER
• Synonyms: acetate,(Z)-6-Nonen-1-ol;aceticacidnonenylester;ACETIC ACID CIS-6-NONEN-1-YL ESTER;ACETIC ACID CIS-6-NONENYL ESTER;CIS-6-NONENYL ACETATE;(Z)-non-6-enyl acetate;aceticacidcis-6-nonen-1-ylester92+%;6-Nonen-1-ol, acetate, (6Z)-
• CAS NO: 76238-22-7
• Molecular Formula: C₁₁H₂₀O₂
• Molecular Weight: 184.28
• EINECS: 278-397-7
• Mol File: 76238-22-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 245.7 °C at 760 mmHg
• Flash Point: 106 °C
• Appearance: /
• Density: 0,89 g/cm3
• Refractive Index: 1.4320-1.4380
• CAS DataBase Reference: ACETIC ACID CIS-6-NONEN-1-YL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: ACETIC ACID CIS-6-NONEN-1-YL ESTER(76238-22-7)
• EPA Substance Registry System: ACETIC ACID CIS-6-NONEN-1-YL ESTER(76238-22-7)

Safety Data

• Hazardous Substances Data: 76238-22-7(Hazardous Substances Data)

Usage

General Description

ACETIC ACID CIS-6-NONEN-1-YL ESTER, also known as (Z)-6-NONENYL ACETATE, is a colorless liquid with a fruity odor. It is commonly used as a flavoring agent and fragrance ingredient in various products such as perfumes, soaps, and food items. It is derived from acetic acid and has the chemical formula C10H18O2. This chemical is often used in the manufacturing of cosmetics and household products due to its pleasant scent and ability to enhance the overall fragrance of a product. Additionally, it is also used in the production of insect attractants and repellents.

Upstream product

• 87298-22-4 1-Tetrahydropyranyloxy-non-6(Z)-ene 
• 75-36-5 acetyl chloride 
• 119265-30-4 1,8-diacetoxy-2Z-octene 
• 74-88-4 methyl iodide 
• 60171-36-0 (Z)-Oct-2-ene-1,8-diol 
• 40709-05-5 (E/Z)-6-Nonen-1-ol 
• 87298-23-5 2-(trans-6,7-Epoxynonoxy)-tetrahydropyran 
• 55305-36-7 (E/Z)-2-(6-Nonenoxy)-tetrahydropyran 
• 68760-65-6 (6-hydroxyhexyl)triphenylphosphonium bromide 
• 31502-19-9 (Z)-6-nonenol 
• 108-24-7 acetic anhydride 

Downstream Products

• 143-13-5 nonyl acetate 
• 103109-24-6 9-hydroxyl nonanyl acetate 
• 616223-76-8 8-hydroxynonyl acetate 

Relevant articles and documents

Fe(PyTACN)-catalyzed cis-dihydroxylation of olefins with hydrogen peroxide

A family of iron complexes with general formula [Fe(II)( R,Y,XPyTACN)(CF3SO3)2], where R,Y,XPyTACN=1-[2′-(4-Y-6-X-pyridyl)methyl]-4,7-dialkyl-1,4, 7-triazacyclononane, X and Y refer to the groups at positions 4 and 6 of the pyridine, respectively, and R refers to the alkyl substitution at N-4 and N-7 of the triazacyclononane ring, are shown to be catalysts for efficient and selective alkene oxidation (epoxidation and cis-dihydroxylation) employing hydrogen peroxide as oxidant. Complex [Fe(II)(Me,Me,HPyTACN)(CF 3SO3)2] (7), was identified as the most efficient and selective cis-dihydroxylation catalyst among the family. The high activity of 7 allows the oxidation of alkenes to proceed rapidly (30 min) at room temperature and under conditions where the olefin is not used in large amounts but instead is the limiting reagent. In the presence of 3 mol% of 7, 2 equiv. of H2O2 as oxidant and 15 equiv. of water, in acetonitrile solution, alkenes are cis-dihydroxylated reaching yields that might be interesting for synthetic purposes. Competition experiments show that 7 exhibits preferential selectivity towards the oxidation of cis olefins over the trans analogues, and also affords better yields and high [syn-diol]/[epoxide] ratios when cis olefins are oxidized. For aliphatic substrates, reaction yields attained with the present system compare favourably with state of the art Fe-catalyzed cis-dihydroxylation systems, and it can be regarded as an attractive complement to the iron and manganese systems described recently and which show optimum activity against electron-deficient and aromatic olefins. Copyright

Herstellung von (E)- und (Z)-6-Nonen-1-yl-acetat

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