76250-81-2

Basic information

• Product Name: N,N-diisopropyl-2,3-diphenylpropylamine methiodide salt
• CAS NO: 76250-81-2
• Molecular Weight: 437.407
• Mol File: 76250-81-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-diisopropyl-2,3-diphenylpropylamine methiodide salt(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-diisopropyl-2,3-diphenylpropylamine methiodide salt(76250-81-2)
• EPA Substance Registry System: N,N-diisopropyl-2,3-diphenylpropylamine methiodide salt(76250-81-2)

Safety Data

• Hazardous Substances Data: 76250-81-2(Hazardous Substances Data)

Upstream product

• 10342-97-9 N,N-diisopropylmethylamine 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 76233-27-7 N,N-diisopropyl-2,3-diphenylpropylamine 
• 74-88-4 methyl iodide 

Relevant articles and documents

Photochemical Addition of Tertiary Amines to Stilbene. Stereoelectronic Control of Tertiary Amine Oxidation.

The photochemical addition reactions of seven nonsymmetrical tertiary amines with singlet trans-stilbene are described.Addition of methyldiisopropylamine or isopropyldimethylamine is highly selective for formation of the least substituted α-amino radical, whereas addition of several less highly branched amines is relatively nonselective.The product isotope effect for tert-butylmethyl(trideuteriomethyl)amine is 2.2+/-0.2.Product selectivity is determined by the orientation of the deprotonation of an aminium radical intermediate by the stilbene radical anion.Selectiveoxidation results from e stereoelectronic effect which is most evident w hen one more alkyl group is highly branched.