76287-58-6

Basic information

• Product Name: 1-Bromo-4-((E)-hex-1-enyl)-benzene
• Synonyms: 1-Bromo-4-((E)-hex-1-enyl)-benzene
• CAS NO: 76287-58-6
• Molecular Weight: 239.155
• Mol File: 76287-58-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Bromo-4-((E)-hex-1-enyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Bromo-4-((E)-hex-1-enyl)-benzene(76287-58-6)
• EPA Substance Registry System: 1-Bromo-4-((E)-hex-1-enyl)-benzene(76287-58-6)

Safety Data

• Hazardous Substances Data: 76287-58-6(Hazardous Substances Data)

Upstream product

• 71434-62-3 (+/-)-p-bromophenyl-1-hexanol 
• 1122-91-4 4-bromo-benzaldehyde 
• 693-25-4 n-pentylmagnesium bromide 

Downstream Products

• 23703-22-2 1-bromo-4-n-hexylbenzene 
• 76287-45-1 Tris-(4-n-hexylphenyl)phosphin 

Relevant articles and documents

Preparation and Properties of Tertiary p-Alkylarylphosphines containing Straight-chain Alkyl Groups

A series of tris(p-alkylaryl)phosphines with straight-chain alkyl groups, P(p-C6H4-CnH2n+1)3 where n=2-9, have been prepared by reaction of phosphorus trichloride with the Grignard reagent derived from the corresponding p-bromoalkylbenzene.When n=2 and 3 the phosphines are crystalline solids, but for n>3 they are viscous oils up to n=9, which is a waxy solid.The phosphines have been characterised by microanalysis, and i.r., 1H and 31P n.m.r., and mass spectrometry.The p-substituted-arylphosphines are more sensitive than triphenylphosphine to air; aerial oxidation converts them exclusively into the corresponding phosphine oxides, in contrast to trialkylphosphines which are oxidised to a complex mixture of products.The complexing ability of the new phosphines (PAr3) is demonstrated by their ready displacement of 1,5-cyclo-octadiene (cod) from (M=Pd and Pt) to yield trans- and cis-, respectively.