764-57-8Relevant articles and documents
DIASTEREOSELECTIVE SYNTHESIS OF (E)-1-TRIMETHYLSILYL-3-EN-1-YNES BY PALLADIUM-CATALYZED CROSS-COUPLING REACTION BETWEEN TRIMETHYLSILYLETHYNYLZINC CHLORIDE AND STEREOISOMERIC MIXTURES OF 1-BROMO-1-ALKENES
Andreini, Bianca Patrizia,Carpita, Adriano,Rossi, Renzo
, p. 5533 - 5534 (2007/10/02)
In the stereospecific palladium-catalyzed cross-coupling reaction of trimethylsilylethynylzinc chloride, (E)-1-bromo-1-alkenes react preferentially in the presence of the corresponding (Z)-stereoisomers.