764-58-9

Basic information

• Product Name: (E)-3-Hepten-1-yne
• Synonyms: (E)-3-Hepten-1-yne
• CAS NO: 764-58-9
• Molecular Formula: C₇H₁₀
• Molecular Weight: 94.15
• Mol File: 764-58-9.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (E)-3-Hepten-1-yne(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-Hepten-1-yne(764-58-9)
• EPA Substance Registry System: (E)-3-Hepten-1-yne(764-58-9)

Safety Data

• Hazardous Substances Data: 764-58-9(Hazardous Substances Data)

Upstream product

• 93336-35-7 4-ethylsulfanyl-hepta-2,3-diene 
• 123-72-8 butyraldehyde 
• 106-96-7 propargyl bromide 
• 60216-46-8 trans-1-Trimethylsilylhept-3-en-1-yn 
• 60468-23-7 (E)/(Z)-1-bromo-1-pentene 
• 109-67-1 1-penten 
• 31849-76-0 pentenyl bromide 

Downstream Products

• 70737-20-1 (cis-2-bromo-vinyl)-trimethyl-silane 
• 126262-21-3 (1E,5E)-1-trimethylsilyl-1,5-nonadien-3-yne 
• 29576-70-3 (2E,6E)-1-acetoxy-2,6-decadien-4-yne 
• 29576-70-3 Acetic acid (2E,6Z)-deca-2,6-dien-4-ynyl ester 
• 224967-47-9 (+)-(2R,3R,5R)-2-hydroxymethyl-3-(1,3-heptadienyl)-5-(tert-butyldimethylsiloxy)cyclohexanone 
• 128856-71-3 (2R,3R,5R)-2,3-bis-(O-trimethylsilyl)-2,3-dihydroxy-5-(1',3'-E,E-1'-heptadienyl)-cyclohexanone 
• 140224-89-1 3-hepta-1,3-dienyl-5,6-dihydroxy-2-hydroxymethylcyclohexanone 
• 251959-53-2 (2R,3S,5R,6R)-3-((1E,3E)-Hepta-1,3-dienyl)-2-hydroxymethyl-5,6-bis-trimethylsilanyloxy-cyclohexanone 
• 186900-37-8 (5S,6R)-5-((1E,3E)-hepta-1,3-dienyl)-6-hydroxymethyl-cyclohex-2-enone 
• 186900-40-3 penihydrone 
• 1002-94-4 (10Z,12E)-hexadecadien-1-ol 
• 864-40-4 Hexadecadien-(10c,12t)-yl-⁽¹⁾-4'-nitro-azobenzol-carbonsaeure-⁽⁴⁾-ester 

Relevant articles and documents

Applications of crotonyldiisopinocampheylboranes in synthesis: Total synthesis of restrictinol

The total synthesis of restrictinol, the hydrolysis product of the antifungal natural product restricticin, starting from commercially available methyl (S)-(+)-3-hydroxy-2-methylpropionate is described. Key stages in the strategy involved (i) the use of Brown's allylboration chemistry to construct an acyclic intermediate bearing three of the four stereogenic centers of the natural product, (ii) formation of a C-glycosidic vinyl iodide, and (iii) introduction of the triene side chain via a Suzuki coupling reaction.

DIASTEREOSELECTIVE SYNTHESIS OF (E)-1-TRIMETHYLSILYL-3-EN-1-YNES BY PALLADIUM-CATALYZED CROSS-COUPLING REACTION BETWEEN TRIMETHYLSILYLETHYNYLZINC CHLORIDE AND STEREOISOMERIC MIXTURES OF 1-BROMO-1-ALKENES

In the stereospecific palladium-catalyzed cross-coupling reaction of trimethylsilylethynylzinc chloride, (E)-1-bromo-1-alkenes react preferentially in the presence of the corresponding (Z)-stereoisomers.