76437-39-3Relevant articles and documents
Reaction of nitroalkanes with polyfluoroaromatic compounds
Vaidyanathaswamy,Radha,Dharani,Raguraman,Anand, Rajdeep
, p. 33 - 37 (2013/01/15)
Nitromethane and nitroethane in the presence of DBU attack preferentially the para position of pentafluorobenzonitrile and methyl pentafluorobenzoate to give the addition products in good yield. The resulting nitro compounds can be converted to tetrafluorotoluene or ethyl benzene derivatives by tri-n-butyltin hydride. TiCl3 solution neatly transforms the nitroethyl compounds into corresponding ketones. With a base, the nitro compounds can be used to extend chain length using Michael acceptors like ethyl acrylate and acrylonitrile.
Polyfluoroaromatic nitriles
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, (2008/06/13)
The difunctional polyfluoroaromatic compounds represented by the formula STR1 wherein X and Y are identical and are selected from the class consisting of --COOR1, --CH2 NH2, --CH2 NCO and STR2 wherein R1/s
Halogenated esters
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, (2008/06/13)
Compounds of formula I wherein R1 and R2 are each selected from halomethyl and halo and R is nitro, cyano, lower alkoxycarbonyl, lower alkylcarbonyl, or di- or trifluoromethyl, and n has a value of zero to four, and compositions comprising them are useful as insecticides in agriculture, horticulture and other outlets. They may optionally be combined with other pesticides and/or synergists. The compounds may be prepared by conventional esterification processes from the corresponding acids and appropriately substituted benzyl alcohols or halides, some of which are novel. STR1
