765-12-8Relevant articles and documents
Development of a highly efficient catalytic method for synthesis of vinyl ethers
Okimoto, Yoshio,Sakaguchi, Satoshi,Ishii, Yasutaka
, p. 1590 - 1591 (2007/10/03)
A new method for the preparation of alkyl vinyl ethers has been developed. Thus, various types of alkyl vinyl ethers were synthesized by the reaction of alcohols with vinyl acetate under the influence of a catalytic amount of [Ir(cod)Cl]2 combined with Na2CO3 in good to excellent yields. Copyright
Nucleophilic addition to acetylenes in superbasic catalytic systems. IX. Anions of oligo(ethylene glycol)s and monomethyl ethers thereof
Parshina,Sokolyanskaya,Nosyreva,Scotheim,Zefirov,Trofimov
, p. 202 - 206 (2007/10/03)
In superbasic system KOH-DMSO increases velocity and selectivity of nucleophilic addition of oligo(ethylene glycol)s and their monometyl ethers to acetylene. Accumulation of ethylene oxide units in the molecule additionally activates it to vinylation process due to formation of crown-like structure which increases the basicity of the medium and nucleophilicity of the reacting anions.