76584-01-5

Basic information

• Product Name: Furan, 2-(3-phenyl-1-propenyl)-, (E)-
• CAS NO: 76584-01-5
• Molecular Formula: C13H12O
• Molecular Weight: 184.238
• Mol File: 76584-01-5.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Furan, 2-(3-phenyl-1-propenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Furan, 2-(3-phenyl-1-propenyl)-, (E)-(76584-01-5)
• EPA Substance Registry System: Furan, 2-(3-phenyl-1-propenyl)-, (E)-(76584-01-5)

Safety Data

• Hazardous Substances Data: 76584-01-5(Hazardous Substances Data)

Upstream product

• 37542-90-8 2-[(2E)-3-phenyl-2-propen-1-yl]furan 
• 27393-97-1 (E)-3-(2-furanyl)-2-propen-1-ol 
• 98-80-6 phenylboronic acid 
• 675607-92-8 (E)-3-furan-2-yl-prop-2-en-1-ol methyl carbonate 
• 699-18-3 2-(2-nitrovinyl)furan 
• 1539-57-7 diethyl 2,6-dimethyl-4-benzyl-1,4-dihydropyridine-3,5-dicarboxylate 
• 39511-08-5 (E)-3-(2-furanyl)-2-propenal 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 4173-48-2 (1-((2-methoxypropan-2-yl)oxy)prop-2-yn-1-yl)benzene 
• 98-01-1 furfural 
• 699-18-3 2-[(E)-2-nitroethenyl]furan 
• 108-88-3 toluene 
• 539-47-9 3-(fur-2-yl)crotonic acid 
• 1403462-85-0 C₂₁H₂₁NO₅S₂ 

Downstream Products

• 37542-90-8 2-[(2E)-3-phenyl-2-propen-1-yl]furan 
• 502-22-7 benzyl(2-furyl)acetylene 

Relevant articles and documents

Palladium-catalyzed reaction of γ-silylated allyl acetates proceeding through 1,2-shift of a substituent on silicon

The palladium-catalyzed reaction of γ-silylated allyl acetates with water in the presence of CsF induces a previously unprecedented 1,2-shift of a substituent on silicon to produce allylsilanes in situ. The catalytic activity of the palladium increased when using an electron-poor phosphine ligand possessing fluorinated substituents. Further investigation of the reaction revealed that the approximate order of the migratory aptitude of groups from silicon was PhC≡C, allyl > Bn > Ph, vinyl > alkyl (Me, Et). A density functional theory study was employed to explore the reaction mechanism. Finally, the Hosomi–Sakurai-type allylation of aldehydes with in situ-generated α,γ-disubstituted allylsilanes was also investigated.

Nickel-Catalyzed Direct Coupling of Allylic Alcohols with Organoboron Reagents

The direct coupling of allylic alcohols with arylboronic acids or their derivatives catalyzed by Ni(cod)2 in the presence of a catalytic amount of base has been developed. A wide variety of allylic substrates or arylboronic acids turned out to be applicable to this catalytic system. The present method does not require the use of ligands for stabilizing the nickel catalyst in most cases or additional activators for activation of allylic alcohols.

Alkyl transfer from C-C cleavage: Replacing the nitro group of nitro-olefins

Alkyl substituted Hantzsch esters are rationally used as alkylation reagents to replace the nitro groups of nitro olefins to give excellent yields of trans-olefins. The reaction mechanism is considered to proceed through a free radical mechanism, which is different from the corresponding transfer alkylation of imines. This journal is the Partner Organisations 2014.