76626-59-0

Basic information

• Product Name: C₆H₉O₃
• Synonyms: C₆H₉O₃
• CAS NO: 76626-59-0
• Molecular Weight: 129.136
• Mol File: 76626-59-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₆H₉O₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₆H₉O₃(76626-59-0)
• EPA Substance Registry System: C₆H₉O₃(76626-59-0)

Safety Data

• Hazardous Substances Data: 76626-59-0(Hazardous Substances Data)

Upstream product

• 766-32-5 4-Methyl-2,6,7-trioxabicyclo<2.2.2>octane 

Relevant articles and documents

Kinetic Applications of Electron Paramagnetic Resonance Spectroscopy. 36. Stereoelectronic Effects in Hydrogen Atom Abstraction from Ethers

Relative rates of hydrogen atom abstraction by photogenerated tert-butoxyl from a variety of cyclic and acyclic ethers, acetals, and orthoformates have been measured at -60 deg C by an EPR spectroscopic technique.There is a pronounced stereoelectronic effect which produces high rates of abstraction from those C-H bonds adjacent to oxygen which have a relatively small dihedral angle (ca. 30 deg) with respect to the p-type orbital(s) on the oxygen(s).For C-H bonds which have a large dihedral angle (ca. 90 deg) abstraction is very much slower.The barrier to inversion of the 2-methoxy-1,3-dioxolan-2-yl radical is 10 kcal/mol.