76644-12-7Relevant articles and documents
Kinetics and Mechanism of Reaction of Thiourea Nitrite in a Highly Ionic Medium
Pare, J. R. Jocelyn
, p. 1116 - 1119 (2007/10/02)
The title reaction proceeds by a multistep mechanism with two major paths.Production of colloidal sulphur is also noted.A novel mechanistic approach is proposed, based on the kinetic data obtained and some previous work.The reaction is shown to be a second-order process involving an unusual S-nitrosation of thiourea.