76681-84-0

Basic information

• Product Name: 2-<(1,2-dioxo-2-(methylamino)ethyl)phenylamino>benzoic acid methyl ester
• Synonyms: 2-<(1,2-dioxo-2-(methylamino)ethyl)phenylamino>benzoic acid methyl ester
• CAS NO: 76681-84-0
• Molecular Weight: 312.325
• Mol File: 76681-84-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-<(1,2-dioxo-2-(methylamino)ethyl)phenylamino>benzoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-<(1,2-dioxo-2-(methylamino)ethyl)phenylamino>benzoic acid methyl ester(76681-84-0)
• EPA Substance Registry System: 2-<(1,2-dioxo-2-(methylamino)ethyl)phenylamino>benzoic acid methyl ester(76681-84-0)

Safety Data

• Hazardous Substances Data: 76681-84-0(Hazardous Substances Data)

Upstream product

• 85-91-6 Methyl N-methylanthranilate 
• 70060-88-7 2-<(2-chloro-1,2-dioxoethyl)phenylamino>benzoate 
• 62-53-3 aniline 
• 76681-82-8 2-<(2-(methylamino)-1,2-dioxoethyl)phenylamino>benzoic acid methyl ester 

Downstream Products

• 91-40-7 2-(phenylamino)benzoic acid 
• 33828-98-7 3-phenylimino-2-indolinone 
• 85-91-6 Methyl N-methylanthranilate 

Relevant articles and documents

A Novel Oxamide Rearrangement

An efficient, base-induced rearrangement of 2-benzoic acid methyl ester (7a) to the isomeric 2-benzoic acid methyl ester (27a) is described.This novel rearrangement must proceed through a spiro intermediate wherein benzoate is acting as a Michael receptor.When 2-benzoic acid methyl ester (28) - an oxamide which would produce a degenerate spiro intermediate - was subjected to rearrangement conditions, the product obtained was 1,3-dimethyl-2,4-(1H,3H)quinazolinedione (29).This latter transformation may have proceeded via a benzodiazepinetrione intermediate.