767-78-2

Basic information

• Product Name: 1-deutero-2,4,6-trifluorobenzene
• Synonyms: 1-deutero-2,4,6-trifluorobenzene
• CAS NO: 767-78-2
• Molecular Weight: 133.077
• Mol File: 767-78-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-deutero-2,4,6-trifluorobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-deutero-2,4,6-trifluorobenzene(767-78-2)
• EPA Substance Registry System: 1-deutero-2,4,6-trifluorobenzene(767-78-2)

Safety Data

• Hazardous Substances Data: 767-78-2(Hazardous Substances Data)

Upstream product

• 182482-25-3 2,4,6-trifluorophenylboronic acid 
• 372-38-3 1,3,5-trifluorobenzene 
• 811-98-3 d⁽⁴⁾-methanol 
• 7789-20-0 water-d2 

Relevant articles and documents

Deuterium Exchange between Arenes and Deuterated Solvents in the Absence of a Transition Metal: Synthesis of D-Labeled Fluoroarenes

Fluoroarenes can be selectively deuterated by H/D exchange with common deuterated solvents in the presence of a catalytic amount of an alkali metal carbonate or, for the less acidic arenes, stoichiometric quantities of potassium phosphate. This is a susta

Metal-Free sp2-C-H Borylation as a Common Reactivity Pattern of Frustrated 2-Aminophenylboranes

C-H borylation is a powerful and atom-efficient method for converting affordable and abundant chemicals into versatile organic reagents used in the production of fine chemicals and functional materials. Herein we report a facile C-H borylation of aromatic and olefinic C-H bonds with 2-aminophenylboranes. Computational and experimental studies reveal that the metal-free C-H insertion proceeds via a frustrated Lewis pair mechanism involving heterolytic splitting of the C-H bond by cooperative action of the amine and boryl groups. The adapted geometry of the reactive B and N centers results in an unprecedentently low kinetic barrier for both insertion into the sp2-C-H bond and intramolecular protonation of the sp2-C-B bond in 2-ammoniophenyl(aryl)- or -(alkenyl)borates. This common reactivity pattern serves as a platform for various catalytic reactions such as C-H borylation and hydrogenation of alkynes. In particular, we demonstrate that simple 2-aminopyridinium salts efficiently catalyze the C-H borylation of hetarenes with catecholborane. This reaction is presumably mediated by a borenium species isoelectronic to 2-aminophenylboranes.

Polyfluoroorganoboron-oxygen compounds. 2 [1]: Base-catalysed hydrodeboration of polyfluorophenyl(dihydroxy)boranes

Polyfluorinated phenyl(dihydroxy)boranes C6H5-nFnB(OH)2 (n = 3 - 5) underwent hydrodeboration (formal replacement of the (dihydroxy)boryl group by hydrogen) in the presence of bases (MeOH, 33% H2O-MeO