76890-09-0

Basic information

• Product Name: 2-(2,5-dimethylphenyl)quinoline
• CAS NO: 76890-09-0
• Molecular Weight: 233.313
• Mol File: 76890-09-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(2,5-dimethylphenyl)quinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2,5-dimethylphenyl)quinoline(76890-09-0)
• EPA Substance Registry System: 2-(2,5-dimethylphenyl)quinoline(76890-09-0)

Safety Data

• Hazardous Substances Data: 76890-09-0(Hazardous Substances Data)

Upstream product

• 20389-07-5 2-(2,5-dimethyl-phenyl)-quinoline-4-carboxylic acid 
• 5344-90-1 2-Aminobenzyl alcohol 
• 2142-73-6 1-(2,5-dimethylphenyl)-1-ethanone 
• 91-56-5 indole-2,3-dione 
• 91-22-5 quinoline 
• 553-94-6 4-bromo-m-xylene 

Relevant articles and documents

Pyridine mediated transition-metal-free direct alkylation of anilines using alcohols: via borrowing hydrogen conditions

Herein, we report pyridine and other similar azaaromatics as efficient biomimetic hydrogen shuttles for a transition-metal-free direct N-alkylation of aryl and heteroaryl amines using a variety of benzylic and straight chain alcohols. Mechanistic studies including deuterium labeling and the isolation of dihydro-intermediates of the benzannulated pyridine confirmed the role of pyridine and a borrowing hydrogen process operating in these reactions. In addition, we have extended this methodology for the development of dehydrogenative synthesis of quinolines and indoles, as well as the transfer hydrogenation of ketones. This journal is

SYNTHESIS OF METHYL-SUBSTITUTED INDENOQUINOLINES, INDENOQUINOXALINES, AND THEIR KETO DERIVATIVES AND INVESTIGATION OF THEIR STRUCTURES

A series of difficultly obtainable and previously unknown methyl homologs of 11H-indenoquinoline, 11H-indenoquinoxaline, and the corresponding 11-keto derivatives were synthesized by new convenient methods, and their structures were investigated.By PMR with lanthanide shift reagents Eu(dpm)3, Pr(dpm)3 and Yb(dpm)3 it was established that the indenoquinolines and ketoindenoquinoxalines do not coordinate with any of the indicated reagents, while the 11-keto derivatives of the indenoquinolines, like those of the indenoquinoxalines, only enter coordination with Yb(dpm)3 at the oxygen atom in the case of the ketoindenoqui nolines and at the N10 nitrogen atom in the case of the indenoquinoxalines.The results from quantum-chemical calculations on the keto derivatives of the indenoquinoline and indenoquinoxaline series are given, and the reasons for the various directions of coordination of Yb(dpm)3 with this type of compound are discussed.