76904-91-1

Basic information

• Product Name: (R)-3-((R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionyloxy)-nonanoic acid methyl ester
• CAS NO: 76904-91-1
• Molecular Weight: 404.427
• Mol File: 76904-91-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-3-((R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionyloxy)-nonanoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-((R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionyloxy)-nonanoic acid methyl ester(76904-91-1)
• EPA Substance Registry System: (R)-3-((R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionyloxy)-nonanoic acid methyl ester(76904-91-1)

Safety Data

• Hazardous Substances Data: 76904-91-1(Hazardous Substances Data)

Upstream product

• 20445-33-4 (R)-methoxytrifluoromethylphenylacetyl chloride 
• 28941-56-2 methyl ester of (R)-3-hydroxynonanoic acid 
• 33796-87-1 (R)-3-hydroxynonanoic acid 
• 159690-58-1 (R)-7-benzyloxacycloheptan-2-one 
• 119103-81-0 (R)-3-acetoxynonanoic acid 
• 159690-73-0 (R)-1-phenyloctan-2-yl acetate 

Relevant articles and documents

Application of Microbial Enantiofacially Selective Hydrolysis in Natural Product Synthesis

Pichia farinosa IAM 4682 mediated enantiofacially selective hydrolysis worked efficiently (65-70percent yield) on the interface-bioreactor in a reproducible manner, which established the product, (R)-2-benzylcyclohexanone (84-87percent e.e.), to be the starting material for the synthesis of optically active natural products.Methyl (R)-3-hydroxy-12-methyltridecanoate, a constituent of lipopolysaccharide, and (R)-1,3-nonanediol, a secretion of cucumber fly, were synthesized via this common intermediate, of which the optically active secondary alcohol moiety was derived from the above chiral ketone by Baeyer-Villiger oxidation.Final products were enantiomerically enriched to 94-95percent e.e., by the lipase-mediated enantioselective transesterification, which could remove the minor enantiomer as the corresponding acetate.