769958-21-6Relevant articles and documents
Silenes as novel synthetic reagents: Identification of a practical method for silene generation and trapping
Berry, Malcolm B.,Griffiths, Russell J.,Sanganee, Mahesh J.,Steel, Patrick G.,Whelligan, Daniel K.
, p. 2381 - 2392 (2007/10/03)
The elucidation of a robust and reliable sequence for the generation of highly reactive transient silenes from simple aldehydes is described. The key step involves a silyl-modified Peterson olefination which critically depends on the presence of a sub-sto