77-82-7

Basic information

• Product Name: D-Arabino-2-hexulose-1,6-bis(dihydrogenphosphat)
• Synonyms: 15499-52-2 (Tetra-potassium salt);23558-08-9 (Unspecified hydrochloride salt);23784-19-2 (Tetra-hydrochloride salt);26177-85-5 (Di-hydrochloride salt);34378-77-3 (Unspecified calcium salt);38099-82-0 (Tri-hydrochloride salt);6035-52-5 (Barium[1:2] salt);6055-82-9 (Calcium[1:2] salt)
• CAS NO: 77-82-7
• Molecular Weight: 340.115682
• Mol File: 77-82-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: D-Arabino-2-hexulose-1,6-bis(dihydrogenphosphat)(CAS DataBase Reference)
• NIST Chemistry Reference: D-Arabino-2-hexulose-1,6-bis(dihydrogenphosphat)(77-82-7)
• EPA Substance Registry System: D-Arabino-2-hexulose-1,6-bis(dihydrogenphosphat)(77-82-7)

Safety Data

• Hazardous Substances Data: 77-82-7(Hazardous Substances Data)

Upstream product

• 57-04-5 dihydroxyacetone phosphate 
• 20283-52-7 D-glyceraldehyde 3-phosphate 

Relevant articles and documents

Synthesis of Sugars by Aldolase-Catalyzed Condensation Reactions

Dihydroxyacetone phosphate was prepared in 200-mmol scale from dihydroxyacetone by two procedures: reaction with phosphorus oxytrichloride and glycerol kinase catalyzed phosphorylation using ATP with in situ regeneration of ATP by phosphoenolpyruvate or acetyl phosphate.Dihydroxyacetone phosphate was converted to fructose 6-phosphate in 80percent yield by exposure to a mixture of co-immobilized triosephosphate isomerase and aldolase followed by acid hydrolysis of the condensation product fructose 1,6-bisphosphate.Fructose 6-phosphate was subsequently converted by chemical and enzymatic schemes into fructose, glucose 6-phosphate, and glucose.Practical procedures are described for the preparation of D- and L-glyceraldehyde 3-phosphate and for several hexoses labeled with 13C in the C-2 and C-2,5 positions.