77014-10-9Relevant articles and documents
Fluorescent micellar nanoparticles by self-assembly of amphiphilic, nonionic and water self-dispersible polythiophenes with "hairy rod" architecture
Cianga, Luminita,Bendrea, Anca-Dana,Fifere, Nicusor,Nita, Loredana Elena,Doroftei, Florica,Ag, Didem,Seleci, Muharrem,Timur, Suna,Cianga, Ioan
, p. 56385 - 56405 (2015/02/18)
Polymers with "hairy-rod" architecture having oligo/polythiophene (PTh) as main chain and poly (ethylene glycol) (PEG) (Mn = 2000) as flexible side chains were obtained by combining the "macromonomer technique" with specific methods for the syn
Synthesis and properties of light-emitting polythiophene derivatives bearing terphenyl mesogenic pendant
Chen, Lie,Chen, Yiwang,Zhou, Weihua,Li, Fan,He, Xiaohui,Tang, Ben Zhong
experimental part, p. 70 - 83 (2011/05/03)
A series of polythiophenes containing terphenyl mesogenic side chain at the third position through ester bonding was synthesized by dehalogenative polycondensation. The thiophene monomers 2,5-bromo-3-{[(4-(4'-cyano) terphenyloxy)carbonyl]-methyl]}-thiophene [M(CN)] and 2,5-bromo-3-{[(4-(4'- methoxy)terphenyloxy)-carbonyl]methyl}-thiophene [M(OCH3)] were prepared via Suzuki reation and esterification reactions, in sequence. The structures and properties of the monomers and polymers were characterized and evaluated with nuclear magnetic resonance, infrared spectroscopy, thermogravimetry, differential scanning calorimetry, polarized optical microscopy, ultraviolet spectroscopy, and photoluminescence. All of the polymers were stable, losing little of their weights when heated to 300°C. The polymers showed good solubility and could be dissolved in common solvents such as CHCl3, THF, DMF, etc. The monomers exhibited enantiotropic SmAd phases with a bilayer arrangement in the heating and cooling processes. Due to short spacer methylene ester between the bulk terphenyl mesogenic side chain and rigid polythiophene main chain, the polymers could not exhibit liquid crystallinty at elevated temperature. The existence of the chromophoric terphenyl core endows the polymers with high photoluminescence. When their CH2Cl2 solutions were photoexcited, the polymers emitted a strong UV light about 400nm.
Synthesis and properties of liquid crystalline polythiophene and polythienylenevinylene derivatives
Osaka, Itaru,Goto, Hiromasa,Itoh, Kikuo,Akagi, Kazuo
, p. 339 - 346 (2007/10/03)
Liquid crystalline polythiophene (LC-PTs) and polythienylenevinylene (LC-PTVs) derivatives with various length of methylene spacer in the LC substituents were synthesized. LC-PTs were prepared through dehalogenative polycondensation using Ni(0) complex, a