77018-09-8

Basic information

• Product Name: Pd(C₆H₅NNC(C₆H₄CH₃)NO)2
• CAS NO: 77018-09-8
• Molecular Weight: 582.958
• Mol File: 77018-09-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pd(C₆H₅NNC(C₆H₄CH₃)NO)2(CAS DataBase Reference)
• NIST Chemistry Reference: Pd(C₆H₅NNC(C₆H₄CH₃)NO)2(77018-09-8)
• EPA Substance Registry System: Pd(C₆H₅NNC(C₆H₄CH₃)NO)2(77018-09-8)

Safety Data

• Hazardous Substances Data: 77018-09-8(Hazardous Substances Data)

Upstream product

• 24621-45-2 phenylazo-p-tolylaldoxime 
• 39494-19-4 bis(salicylaldehydato)palladium(II) 
• 15617-18-2 bis(benzonitrile)palladium(II) dichloride 
• 10025-98-6 potassium tetrachloropalladate(II) 

Downstream Products

• 75662-83-8 [PdBrC₆H₅NNC(C₆H₄CH₃)NO]2 

Relevant articles and documents

Bis(arylazo-oximato)palladium(II); Synthesis, Palladium-Nitrogen Bond Lability, and Redox Activity

The synthesis and characterisation of the title complex, , and related mixed-ligand complexes including (A = ortho-metallated azobenzene) are described.The mass spectrum of reveals peaks corresponding to loss of oximato-O and NO from the parent ion.Gaseous HCl cleaves the Pd-N(oxime) bond selectively.Triphenylphosphine cleaves one or both Pd-N(azo) linkages giving and unstable which is also produced by oxidative addition of HL to .In the unidentate and bidentate L groups scramble rapidly at 308 K but slowly at 233 K (1H n.m.r.).Bidentate phosphine and phosphinoarsine cleave the two Pd-N(azo) bonds simultaneously.Unidentate amines, when present in very large excess, produce unstable in which one L is unidentate.Addition of X2 (X= Cl or Br) yields the unstable palladium(IV) complex which is readily reduced to halogeno-bridged palladium(II) species.A cyclic-voltammetric study of the one-electron quasi-reversible reduction of , , etc. at a platinum electrode is briefly reported.