7702-38-7

Basic information

• Product Name: N-(4-bromophenyl)benzamide
• Synonyms: benzamide, N-(4-bromophenyl)-
• CAS NO: 7702-38-7
• Molecular Formula: C₁₃H₁₀BrNO
• Molecular Weight: 276.1286
• Mol File: 7702-38-7.mol
• Article Data: 122

Chemical Properties

• Boiling Point: 293.1°C at 760 mmHg
• Flash Point: 131°C
• Density: 1.496g/cm³
• Vapor Pressure: 0.00176mmHg at 25°C
• Refractive Index: 1.665
• CAS DataBase Reference: N-(4-bromophenyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-bromophenyl)benzamide(7702-38-7)
• EPA Substance Registry System: N-(4-bromophenyl)benzamide(7702-38-7)

Safety Data

• Hazardous Substances Data: 7702-38-7(Hazardous Substances Data)

Usage

General Description

N-(4-Bromophenyl)benzamide is a chemical compound with the formula C13H10BrNO. It is a benzamide derivative, with a bromine atom attached to the phenyl ring. N-(4-Bromophenyl)benzamide is commonly used as a building block in the synthesis of pharmaceuticals and agrochemicals. N-(4-Bromophenyl)benzamide may also have potential applications in the field of materials science, for example in the development of organic semiconductors or liquid crystals. The compound's structure and properties make it a versatile and important intermediate in organic chemistry. However, it is important to handle this chemical with care as it may be hazardous if not used properly.

Upstream product

• 93-98-1 N-phenyl benzoyl amide 
• 574-66-3 Benzophenone oxime 
• 857580-87-1 N-bromo-benzanilide 
• 98-88-4 benzoyl chloride 
• 106-40-1 4-bromo-aniline 
• 18039-42-4 5-Phenyl-1H-tetrazole 
• 147542-38-9 N-(2,4-dibromophenyl)benzamide 
• 93-97-0 benzoic acid anhydride 
• 65-85-0 benzoic acid 
• 25569-87-3 benzoic-p-methylbenzoic anhydride 
• 58618-94-3 benzoic p-methoxybenzoic anhydride 
• 75474-05-4 benzoic-p-nitrobenzoic anhydride 
• 107965-78-6 4-bromo-benzophenone oxime 
• 7726-95-6 bromine 

Downstream Products

• 51300-42-6 N-(4-bromophenyl)benzimidoyl chloride 
• 202328-05-0 N-(2-nitro-4-bromophenyl)benzamide 
• 860556-00-9 3-nitro-benzoic acid-(4-bromo-2,6-dinitro-anilide) 
• 73376-00-8 N-(4-bromophenyl)benzothioamide 
• 93716-83-7 4-amino-6-bromo-2-phenyl-quinazoline 
• 87010-89-7 N₁-methyl-N₁-phenyl-N₂-p-bromophenylbenzamidine 
• 87010-90-0 N₁-methyl-N₁,N₂-di-p-bromophenylbenzamidine 
• 87010-88-6 N₁-methyl-N₁-p-methoxyphenyl-N₂-p-bromophenylbenzamidine 
• 62554-90-9 4-bromo-2,6-dinitroaniline 
• 147542-38-9 N-(2,4-dibromophenyl)benzamide 
• 99234-92-1 N,N-bis-(4-bromophenyl)benzamide 

Relevant articles and documents

Synthesis and characterization of nano-cellulose immobilized phenanthroline-copper (I) complex as a recyclable and efficient catalyst for preparation of diaryl ethers, N-aryl amides and N-aryl heterocycles

Functionalized nanocellulose was prepared and employed for immobilization of phenanthroline-copper(I) complex to afford cellulose nanofibril grafted heterogeneous copper catalyst [CNF-phen-Cu(I)]. This nanocatalyst was well characterized using FT-IR, NMR, XRD, CHNS, AAS, TGA, EDX and SEM. The activities of the synthesized catalyst were examined in the synthesis of diaryl ethers via C-O cross-coupling of phenols and aryl iodides, as well as, the preparation of N-aryl amides and N-aryl heterocycles through C-N cross-coupling of amides and N-H heterocycle compounds with aryl halides. In this trend, various substrates containing electron-donating and electron-withdrawing groups were exploited to evaluate the generality of this catalytic protocol. Accordingly, the catalyst demonstrated remarkable catalytic efficiency for both C-N and C-O cross-coupling reactions, thereby resulting in good to excellent yields of the desired products. Furthermore, the recoverability experiments of the catalyst showed that it can be readily retrieved by simple filtration and successfully reused several times with negligible loss of its catalytic activity.

Regioselective Synthesis of 2° Amides Using Visible-Light-Induced Photoredox-Catalyzed Nonaqueous Oxidative C-N Cleavage of N, N-Dibenzylanilines

A visible-light-driven photoredox-catalyzed nonaqueous oxidative C-N cleavage of N,N-dibenzylanilines to 2° amides is reported. Further, we have applied this protocol on 2-(dibenzylamino)benzamide to afford quinazolinones with (NH4)2S2O8 as an additive. Mechanistic studies imply that the reaction might undergo in situ generation of α-amino radical to imine by C-N bond cleavage followed by the addition of superoxide ion to form amides.

Method for preparing amide from carboxylic acid under irradiation of blue light by taking iridium and cobalt complexes as catalysts

The invention relates to a method for preparing amide from carboxylic acid under the irradiation of blue light by taking iridium and cobalt complexes as catalysts, and belongs to the field of chemistry. The method comprises the following step of: by taking R substituted carboxylic acid and R1' and R2' substituted amines as raw materials, triphenylphosphine as a deoxidizing agent, [Ir(dF(CF3)ppy)2(dtbbpy)]PF6 as a photocatalyst and Co(dmgH)(dmgH2)Cl2 as a metal complex catalyst, reacting in dichloromethane in an inert atmosphere and under the irradiation of blue light to obtain an amide compound, wherein R is an aryl group, a heteroaryl group, a protected amino group, a substituted alkyl group, a substituted aryl group or a substituted protected amino group, R1' is a hydrogen group, a substituted alkyl group, a phenyl group or a substituted phenyl group, and R2' is a hydrogen group, a substituted alkyl group, a phenyl group or a substituted phenyl group.