77093-90-4Relevant articles and documents
Dehydrogenative N-incorporation: A direct approach to quinoxaline N-oxides under mild conditions
Chen, Feng,Huang, Xiaoqiang,Li, Xinyao,Shen, Tao,Zou, Miancheng,Jiao, Ning
supporting information, p. 10495 - 10499 (2016/02/18)
An efficient method for the synthesis of quinoxaline N-oxides proceeds by the dehydrogenative N-incorporation of simple imines by C(sp2)-H and C(sp3)-H bond functionalization. The overall transformation involves the cleavage of three
Synthesis of Quinoxaline Derivatives through Condensation of 1,2-Diaminobenzenes with β-Keto Sulfoxides
Kano, Shinzo,Shibuya, Shiroshi,Yuasa, Yoko
, p. 1559 - 1561 (2007/10/02)
The reaction of o-phenylenediamine with α-methylsulfinylcyclohexanone and α-methylsulfinylcyclopentanone in the presence of acetic acid afforded 1,2,3,4-tetrahydrophenazine and 2,3-dihydro-1H-cyclopentaquinoxaline, respectively. 3,4-Diaminotoluene and 3,4-diaminochlorobenzene were reacted with α-methylsulfinylacetophenone to give a mixture of the corresponding 6- and 7-substituted 2-phenylquinoxaline.Condensation of 3,4-diaminomethoxybenzene with α-methylsulfinylacetophenone gave 7-methoxy-2-phenylacetophenone, whereas, the same reaction between 3,4-diaminonitrobenzene and α-methylsulfinylacetophenone yielded 6-nitro-2-phenylquinoxaline.