77120-91-3

Basic information

• Product Name: 2-Pentenedioic acid, 2-acetyl-3-[(phenylmethyl)amino]-, diethyl ester
• CAS NO: 77120-91-3
• Molecular Formula: C18H23NO5
• Molecular Weight: 333.384
• Mol File: 77120-91-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Pentenedioic acid, 2-acetyl-3-[(phenylmethyl)amino]-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pentenedioic acid, 2-acetyl-3-[(phenylmethyl)amino]-, diethyl ester(77120-91-3)
• EPA Substance Registry System: 2-Pentenedioic acid, 2-acetyl-3-[(phenylmethyl)amino]-, diethyl ester(77120-91-3)

Safety Data

• Hazardous Substances Data: 77120-91-3(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 570-08-1 diethyl acetylmalonate 
• 463-51-4 Ketene 
• 77120-90-2 3-Benzylamino-2-pentenedioic acid diethyl ester 

Downstream Products

• 77120-92-4 (2R,3S)-3-Benzylamino-2-((R)-1-hydroxy-ethyl)-pentanedioic acid diethyl ester 
• 75321-08-3 (5R,6S)-3-(Diphenoxy-phosphoryloxy)-6-((R)-1-hydroxy-ethyl)-7-oxo-1-aza-bicyclo[3.2.0]hept-2-ene-2-carboxylic acid 4-nitro-benzyl ester 
• 74288-37-2 4-{(2R,3S)-1-(tert-Butyl-dimethyl-silanyl)-3-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-4-oxo-azetidin-2-yl}-3-oxo-butyric acid 4-nitro-benzyl ester 
• 77120-95-7 (2S,3R)-3-Amino-2-((S)-1-hydroxy-ethyl)-pentanedioic acid 5-benzyl ester; hydrochloride 
• 77120-93-5 (2R,3R,4S)-4-Benzylamino-2-methyl-6-oxo-tetrahydro-pyran-3-carboxylic acid; hydrochloride 
• 77120-97-9 {(2R,3S)-1-(tert-Butyl-dimethyl-silanyl)-3-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-4-oxo-azetidin-2-yl}-acetic acid benzyl ester 
• 75321-07-2 4-[(2S,3R)-3-((R)-1-Hydroxy-ethyl)-4-oxo-azetidin-2-yl]-3-oxo-butyric acid 4-nitro-benzyl ester 
• 75321-07-2 4-[(2S,3R)-3-((S)-1-Hydroxy-ethyl)-4-oxo-azetidin-2-yl]-3-oxo-butyric acid 4-nitro-benzyl ester 
• 74288-40-7 (2S,5S,6R)-6-((S)-1-Hydroxy-ethyl)-3,7-dioxo-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 4-nitro-benzyl ester 
• 77120-96-8 benzyl -4-oxoazetidin-2-yl> acetate 
• 64067-13-6 (5R,6S)-6-((R)-1-Hydroxy-ethyl)-3-[2-(4-nitro-benzyloxycarbonylamino)-ethylsulfanyl]-7-oxo-1-aza-bicyclo[3.2.0]hept-2-ene-2-carboxylic acid 4-nitro-benzyl ester 
• 79543-87-6 4-[(2S,3R)-3-((S)-1-Formyloxy-ethyl)-4-oxo-azetidin-2-yl]-3-oxo-butyric acid 4-nitro-benzyl ester 

Relevant articles and documents

3(1-hydoxyethyl)azetidinone compounds and their production

An amino acid compound of the formula: STR1 wherein R is a lower alkyl group, R1 is a hydrogen atom or a protecting group for carboxyl, R2 is a hydrogen atom, a protecting group for amino, an optionally substituted allyl group of the formula: STR2 (wherein R3 and R4 are each a hydrogen atom, a lower alkyl group or an aryl group), a beta-hydroxyethyl group in which the hydroxyl group is optionally protected, a formylmethyl group in which the formyl group is optionally protected, a carboxymethyl group in which the carboxyl group is protected or a 2-furylmethyl group and X is an optionally protected carboxyl group, a hydroxymethyl group in which the hydroxyl group is optionally protected or a substituted mercaptomethyl group of the formula: (wherein R5 is an aryl group or an ar(lower)alkyl group), which is a useful intermediate in the synthesis of 1-alkylcarbapenem compounds.