77176-12-6Relevant articles and documents
The Oxidoreductive 1,3-Rearrangement of 3H-1,4-Benzodiazepines with Semicyclic Hydroxyamidine Structure to 2-Alkylamino-3-acyloxy-3H-1,4-benzodiazepines
Schecker, Heinz-Guenther,Zinner, Gerwalt
, p. 926 - 936 (2007/10/02)
On treatment of N-alkyl-N-(3H-1,4-benzodiazepin-2-yl)-hydroxylamines with carboxylic anhydrides or chlorides an oxidoreductive rearrangement is observed in the presence of protons that leads to 1,4-benzodiazepines bearing the acylated hydroxylaminic oxyge