77287-02-6Relevant articles and documents
Dimethylaluminum Chloride Catalyzed Reactions of Methyl α-Cyanoacrylate with Alkenes
Snider, Barry B.,Phillips, Gary B.
, p. 2563 - 2566 (2007/10/02)
The methyl α-cyanoacrylate-Me2AlCl complex reacts with alkenes to give zwitterion 2.Ring closure on carbon gives the cyclobutane 3 with ca. 90percent retention of alkene stereochemistry, ring closure on oxygen gives dihydropyran 5, and a 1,5-hydrogen shif