77289-31-7

Basic information

• Product Name: {VBr₂(phenylsalicylideneiminate)2}
• CAS NO: 77289-31-7
• Molecular Weight: 603.207
• Mol File: 77289-31-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {VBr₂(phenylsalicylideneiminate)2}(CAS DataBase Reference)
• NIST Chemistry Reference: {VBr₂(phenylsalicylideneiminate)2}(77289-31-7)
• EPA Substance Registry System: {VBr₂(phenylsalicylideneiminate)2}(77289-31-7)

Safety Data

• Hazardous Substances Data: 77289-31-7(Hazardous Substances Data)

Upstream product

• 507-16-4 sulfurous dibromide 
• 14783-75-6 bis(N-phenylsalicylaldiminato)oxovanadium(IV) 

Relevant articles and documents

Electron Spin Resonance Spectra of Dibromo- and Dichloro-complexes of Vanadium(IV)

Reactions of SOCl2 or SOBr2 with a range of 20 vanadyl complexes, (L4= quadridentate or two bidentate ligands), yield solutions containing cis- or trans-dihalogen vanadium(IV) complexes . They are characterised by their e.s.r.spectra and in most cases the unpaired electron is in a dx2- y2 orbital.In some cases both cis and trans isomers can be detected and characterised, because of significant differnces in e.s.r. parameters.In the cas of , the unpaired electron is in a dz2 orbital and the structure is thought to be trigonal prismatic.