77327-87-8

Basic information

• Product Name: 2-Hexenoic acid, 2-[[(phenylmethoxy)carbonyl]amino]-, ethyl ester, (Z)-
• CAS NO: 77327-87-8
• Molecular Formula: C16H21NO4
• Molecular Weight: 291.347
• Mol File: 77327-87-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Hexenoic acid, 2-[[(phenylmethoxy)carbonyl]amino]-, ethyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexenoic acid, 2-[[(phenylmethoxy)carbonyl]amino]-, ethyl ester, (Z)-(77327-87-8)
• EPA Substance Registry System: 2-Hexenoic acid, 2-[[(phenylmethoxy)carbonyl]amino]-, ethyl ester, (Z)-(77327-87-8)

Safety Data

• Hazardous Substances Data: 77327-87-8(Hazardous Substances Data)

Upstream product

• 5753-96-8 ethyl 2-oxohexanoate 
• 621-84-1 O-benzyl carbamate 
• 83026-99-7 2-Benzyloxycarbonylamino-2-diethyloxyphosphoryl-essigsaeure-ethylester 
• 123-72-8 butyraldehyde 
• 71385-55-2 (Z)-2-Amino-hex-2-enoic acid ethyl ester 
• 501-53-1 benzyl chloroformate 

Downstream Products

• 72015-59-9 (Z)-2-Benzyloxycarbonylamino-hex-2-enoic acid 

Relevant articles and documents

Horner Synthesis of Didehydroamino Acid Derivatives in a Liquid-Liquid Two-Phase System

Horner olefination of aldehydes 1 with N-acyl-2-(diethoxyphosphoryl)glycin ethyl esters 2 to give didehydroamino acid derivatives 3 can be performed advantageously in a 20percent aqueous sodium hydroxide/dichloromethane two-phase system in the absence of any typical phase-transfer catalyst.

Dehydrooligopeptides. I. The facile coupling of α-amino acids with α-dehydroamino acids to dehydrodipeptides

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