77379-98-7

Basic information

• Product Name: 2,5-Cyclohexadien-1-one, 4-[bis(dimethylamino)methylene]-2,6-bis(1,1-dimethylethyl)-
• CAS NO: 77379-98-7
• Molecular Formula: C19H32N2O
• Molecular Weight: 304.476
• Mol File: 77379-98-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,5-Cyclohexadien-1-one, 4-[bis(dimethylamino)methylene]-2,6-bis(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Cyclohexadien-1-one, 4-[bis(dimethylamino)methylene]-2,6-bis(1,1-dimethylethyl)-(77379-98-7)
• EPA Substance Registry System: 2,5-Cyclohexadien-1-one, 4-[bis(dimethylamino)methylene]-2,6-bis(1,1-dimethylethyl)-(77379-98-7)

Safety Data

• Hazardous Substances Data: 77379-98-7(Hazardous Substances Data)

Upstream product

• 25751-82-0 2-(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)malononitrile 
• 124-40-3 dimethyl amine 
• 128-39-2 2,6-di-tert-butylphenol 
• 56043-45-9 N,N,N',N'-tetramethylchlorformamidinium chloride 

Downstream Products

• 77379-99-8 2,6-ditert-butyl-7,7-dimorpholinoquinone methide 
• 67341-88-2 4-bis(piperidino)methylene-2,6-di-tert-butyl-2,5-cyclohexadienone 

Relevant articles and documents

SYNTHESIS AND PROPERTIES OF 7,7-DIAMINOQUINONE METHIDES

Diaminoquinone methides Xa-Xe were prepared by aminolysis of the dicyanoquinone methide IX.From the isolated intermediates XI and XIII a four-step mechanism was deduced, involving addition and elimination steps in the order Ad-E-Ad-E.Condensation of N,N,N',N'-tetramethylchloroformamidinium chloride with 2,6-ditert-butylphenol afforded bis(dimethylamino)-quinone methide Xc which on transamination was converted to the diaminoquinone methides Xa and Xb.Analysis of physico-chemical data of diaminoquinone methides leads to the conclusion that their structure can be represented by the zwitterionic formula XVII rather than the quinonoid formula X.