77381-68-1

Basic information

• Product Name: [C1MIm]ClO4
• Synonyms: [C1MIm]ClO4
• CAS NO: 77381-68-1
• Molecular Formula: C5H9ClN2O4
• Molecular Weight: 196.59
• Mol File: 77381-68-1.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: [C1MIm]ClO4(CAS DataBase Reference)
• NIST Chemistry Reference: [C1MIm]ClO4(77381-68-1)
• EPA Substance Registry System: [C1MIm]ClO4(77381-68-1)

Safety Data

• Hazardous Substances Data: 77381-68-1(Hazardous Substances Data)

Usage

General Description

[C1MIm]ClO4 is a chemical compound with the molecular formula C1MIm, which stands for 1-methyl-3-octyl-imidazolium, and is commonly known as a room-temperature ionic liquid. It consists of a cationic imidazolium species and an anionic perchlorate species, making it a type of ionic liquid. [C1MIm]ClO4 is known for its high thermal stability, low volatility, and excellent solubility in a wide range of organic compounds. It is used as a green solvent in various chemical processes, such as catalysis, extraction, and electrochemistry. Additionally, it has shown potential applications in energy storage, gas capture, and pharmaceutical industries. Despite its promising properties, the toxicity and environmental impact of [C1MIm]ClO4 are still under investigation, highlighting the need for further research on its potential risks and benefits in various fields.

Upstream product

• 616-47-7 1-methyl-1H-imidazole 
• 71027-57-1 1,3-dimethyl-1H-imidazol-3-ium bromide 
• 4333-62-4 1,3-dimethylimidazolim iodide 
• 536755-29-0 N,N'-dimethylimidazolium-2-carboxylate 
• 654058-04-5 1-methyl-3-methylimidazol-3-ium dimethyl phosphate 

Relevant articles and documents

Dialkylimidazolium dimethyl phosphates as solvents and catalysts for the Knoevenagel condensation reaction

The reaction between benzaldehyde and ethyl cyanoacetate is investigated in 1,3-dialkylimidazolium salts as solvents. The impact of both ions in these ionic liquids on the yield of the condensation reaction product is examined. Potentiometric titrations a

Ionic liquid-based routes to conversion or reuse of recycled ammonium perchlorate

New, potentially green, and efficient synthetic routes for the remediation and/or re-use of perchloratebased energetic materials have been developed. Four simple organic imidazolium- and phosphonium-based Perchlorate salts/ionic liquids have been synthesi

THE CHELETROPIC FRAGMENTATION OF HYPERVALENT THREE-MEMBERED THIAHETEROCYCLIC INTERMEDIATES

Lithio-imidazolium salts 10, generated in-situ from N'N-dimethylimidazolium salts 9, readily undergo sulfonylation with sulfur dioxide, sulfines, N-sulfinylamines, and thiirane.The resulting zwitterionic species 4 fragment thermally to yield the corresponding imidazolium thione 5 with the hypervalent three-membered thiaheterocyclic intermediates 3 connecting 4 and 5 on the reaction surface.The non-linear cheletropic fragmentation of these relatively stable hypervalent sulfuranes appears to be general for this class of compounds (3 or 4), and the experimental results are in accord with theoretical considerations.