77613-68-4Relevant articles and documents
Thermal Rearrangement of 2,2-Difluorovinylcyclopropane. A Concerted Pathway?
Dolbier, William R.,Al-Sader, B. H.,Sellers, Simon F.,Koroniak, Henryk
, p. 2138 - 2139 (1981)
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THE THERMAL DEAZETATIONS OF FLUORINATED 2,3-DIAZABICYCLOHEPT-2-ENES
Dolbier, William R.,Al-Pekri, Dheya M.
, p. 39 - 44 (2007/10/02)
Thermal deazetation of difluoro- and tetrafluoro-2,3-diazabicyclohept-2-enes proceed via two parallel mechanistic pathways, one involving formation of a diradical via simple N2 loss, and the other proceeding via a retro-dipolar cycloaddition process.A key finding was the absence of isolation of a bicyclopentane product in the difluoro case.