776242-98-9Relevant articles and documents
Photoswitchable Cu(ii)/Cu(i) catalyses assisted by enzyme-like non-covalent interactions in Cu(ii)-melamine coordination polymers for installing CO2/CS2and CF3groups in heterocycles
Zhang, Tiexin,Zang, Hanbin,Gai, Fangyuan,Feng, Zhi,Li, Mochen,Duan, Chunying
, p. 15131 - 15139 (2020)
Despite concerns over the environmental impact of isoelectronic CO2and CS2, they remain useful C1 building blocks with industrial utility, and trifluoromethylation could enhance the lipophilicity and metabolic stability of agrochemic
An anionic: Sod -type terbium-MOF with extra-large cavities for effective anthocyanin extraction and methyl viologen detection
Du, Wei,Zhu, Zhifeng,Bai, Yue-Ling,Yang, Zhen,Zhu, Shourong,Xu, Jiaqiang,Xie, Zhaoxiong,Fang, Jianhui
, p. 5972 - 5975 (2018)
An anionic sod-type zeolitic metal-organic framework [(CH3)2NH2]9{Tb6(η6-TATAT)4(H2O)12}·3Cl·DMA·7H2O [1, H6TATAT = 5,5′,5′′-(1,3,5-tr
The synthesis of a copper metal-organic framework Cu3TDPAT and its application in a Morita-Baylis-Hillman (MBH) reaction
Li, Xiujuan,Luan, Yi,Shang, Hailing,Yang, Yanan,Zhu, Kaicheng
, (2022/01/31)
A highly effective Morita-Baylis-Hillman (MBH) reaction was developed employing Cu (II) derived Cu3TDPAT as the dual-functional metal-organic frameworks (MOFs) catalyst. Four kinds of copper salts were employed as precursors to synthesize Cu3TDPAT. The resultant Cu3TDPAT MOFs were used as catalysts for the MBH model reaction of 4-fluorobenzaldehyde and 2-cyclopentene-1-one under various reaction conditions. The results showed that Cu3TDPAT-c derived from copper nitrate was the optimal catalyst to achieve a high yield (up to 99%). With the presence of aromatic aldehydes and basic triazine groups in Cu3TDPAT, the Lewis acid and base sites in Cu3TDPAT MOF played a significant role during the reaction to effect the formation of C-C single bond between 4-fluorobenzaldehyde and 2-cyclopentene-1-one to generate benzyl methyl acrylonitrile products. In addition, after optimization, this catalyst showed good catalytic performance for the MBH reaction with high thermal stability, reliability, and recyclability. This optimal catalytic performance shows great potential for further development.
Preparation of Highly Porous Metal-Organic Framework Beads for Metal Extraction from Liquid Streams
Yang, Shuliang,Peng, Li,Syzgantseva, Olga A.,Trukhina, Olga,Kochetygov, Ilia,Justin, Anita,Sun, Daniel T.,Abedini, Hassan,Syzgantseva, Maria A.,Oveisi, Emad,Lu, Guanchu,Queen, Wendy L.
supporting information, p. 13415 - 13425 (2020/09/02)
Metal-organic frameworks (MOFs) offer great promise in a variety of gas- and liquid-phase separations. However, the excellent performance on the lab scale hardly translates into pilot- or industrial-scale applications due to the microcrystalline nature of
