7766-03-2

Basic information

• Product Name: trans-2-hydroxy-3-thujene
• CAS NO: 7766-03-2
• Molecular Weight: 152.236
• Mol File: 7766-03-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-2-hydroxy-3-thujene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-2-hydroxy-3-thujene(7766-03-2)
• EPA Substance Registry System: trans-2-hydroxy-3-thujene(7766-03-2)

Safety Data

• Hazardous Substances Data: 7766-03-2(Hazardous Substances Data)

Upstream product

• 563-34-8 α-thujene 
• 177324-96-8 Methanesulfonic acid (1S,3S,4R,5R)-1-isopropyl-4-methyl-bicyclo[3.1.0]hex-3-yl ester 
• 21653-20-3 (-)-3-thujol 
• 53833-85-5 trans-sabinyl acetate 

Relevant articles and documents

A convenient synthesis of trans-sabinene hydrate from (-)-3-thujol via a highly selective ene reaction of singlet oxygen

trans-Sabinene hydrate (1), was synthesized from (-)-3-thujol (2) in four steps. The key step was the selective formation of trans-2-hydroxy-3-thujene (6) by photooxygenation of a 3:1 mixture of 2- and 3-thujenes (4 and 5) obtained from (-)-3-thujol mesylate (3). Hydrogenation of 6 gave compound 1 in 46% overall yield.