77681-08-4

Basic information

• Product Name: Toluene-4-sulfonic acid (S)-3-(1-ethoxy-ethoxy)-butyl ester
• Synonyms: Toluene-4-sulfonic acid (S)-3-(1-ethoxy-ethoxy)-butyl ester
• CAS NO: 77681-08-4
• Molecular Weight: 316.419
• Mol File: 77681-08-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Toluene-4-sulfonic acid (S)-3-(1-ethoxy-ethoxy)-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Toluene-4-sulfonic acid (S)-3-(1-ethoxy-ethoxy)-butyl ester(77681-08-4)
• EPA Substance Registry System: Toluene-4-sulfonic acid (S)-3-(1-ethoxy-ethoxy)-butyl ester(77681-08-4)

Safety Data

• Hazardous Substances Data: 77681-08-4(Hazardous Substances Data)

Upstream product

• 208459-11-4 methyl (1'RS,3R)-3-(1-ethoxyethoxy)butyrate 
• 208459-02-3 (1'RS,3R)-3-(1-ethoxyethoxy)-1-butanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 82614-86-6 (3S)-3-(1'-Aethoxyaethoxy)buttersaeure-aethylester 
• 188525-04-4 (3S)-3-(1'-Aethoxyaethoxy)-1-butanol 
• 56816-01-4 ethyl (S)-3-hydroxybutyrate 
• 109-92-2 ethyl vinyl ether 

Downstream Products

• 82614-88-8 (S)-3-hydroxybutyl toluene-4-sulphonate 

Relevant articles and documents

STUDIES IN POLYETHER SYNTHESIS: SPIROACETAL FORMATION BY DIRECTED BISEPOXYDE CYCLISATION

The synthesis of tricyclic polyether fragments 15 and 20, which incorporate a spiroacetal subunit, using directed bisepoxyde cyclisation is described.

Synthesis of optically active 2s-, and 7s-methyl-1.6-dioxa-spiro[4.5] decane, the pheromone components of Paravespula vulgaris (L.), from S-ethyl lactate.

(-)-2S, 5RS-1 and (-]-7S, 5S-2 are obtained from S-ethyl lactate 4 and their absolute configuration is thus directly correlated. Accurate enantiomeric compositions of intermediates and products were measured by complexation gas chromatography on nickel-, and manganese-bis-3-heptafluorobutyryl-1R-camphorate, 3. It could be conclusively established that the syntheses proceed with a high degree of preservation of configuration.