777067-25-1

Basic information

• Product Name: [(S,S)-bis(α-methylbenzyl)amino]phosphorous dichloride
• Synonyms: [(S,S)-bis(α-methylbenzyl)amino]phosphorous dichloride
• CAS NO: 777067-25-1
• Molecular Weight: 326.205
• Mol File: 777067-25-1.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: [(S,S)-bis(α-methylbenzyl)amino]phosphorous dichloride(CAS DataBase Reference)
• NIST Chemistry Reference: [(S,S)-bis(α-methylbenzyl)amino]phosphorous dichloride(777067-25-1)
• EPA Substance Registry System: [(S,S)-bis(α-methylbenzyl)amino]phosphorous dichloride(777067-25-1)

Safety Data

• Hazardous Substances Data: 777067-25-1(Hazardous Substances Data)

Upstream product

• 21003-56-5 (1S,1'S)-bis(1-phenylethyl)amine 
• 197387-11-4 lithium (S,S)-bis(α-methylbenzyl)amide 

Downstream Products

• 1190295-47-6 (3aS)-2-phenyl-N,N-bis[(S)-1-phenylethyl]-hexahydro-1H-pyrrolo[1,2-c][1,3,2]diazaphosphol-1-amine 
• 1190295-47-6 (3aS)-2-phenyl-N,N-bis[(S)-1-phenylethyl]-hexahydro-1H-pyrrolo[1,2-c][1,3,2]diazaphosphol-1-amine 
• 1494683-45-2 1,1-dibenzyl-N,N-bis((S)-1-phenylethyl)phosphinamine 
• 1494683-50-9 1,1-diisobutyl-N,N-bis((S)-1-phenylethyl)phosphinamine 
• 1494683-40-7 1,1-di(hex-1-ynyl)-N,N-bis((S)-1-phenylethyl)phosphinamine 
• 1494683-37-2 1,1-diallyl-N,N-bis((S)-1-phenylethyl)phosphinamine 
• 1494683-36-1 1,1-dihexyl-N,N-bis((S)-1-phenylethyl)phosphinamine 
• 1494683-34-9 1,1-diethyl-N,N-bis((S)-1-phenylethyl)phosphinamine 
• 21003-56-5 (1S,1'S)-bis(1-phenylethyl)amine 
• 1494683-35-0 1,1-dibutyl-N,N-bis((S)-1-phenylethyl)phosphinamine 

Relevant articles and documents

P-stereogenic pinene-derived phosphoramidites and their use in copper-catalyzed conjugate additions

New P-stereogenic phosphoramidites based on a (-)-pinane framework were synthesized and investigated by NMR spectroscopic methods and single-crystal X-ray structural analysis. The reaction between cis-pinandiol 2 and N,N-dialkylphosphoramidous dichlorides

Enantioselective Alkoxycyclization of 1,6-Enynes with Gold(I)-Cavitands: Total Synthesis of Mafaicheenamine C

Chiral gold(I)-cavitand complexes have been developed for the enantioselective alkoxycyclization of 1,6-enynes. This enantioselective cyclization has been applied for the first total synthesis of carbazole alkaloid (+)-mafaicheenamine C and its enantiomer, establishing its configuration as R. The cavity effect was also evaluated in the cycloisomerization of dienynes. A combination of experiments and theoretical studies demonstrates that the cavity of the gold(I) complexes forces the enynes to adopt constrained conformations, which results in the high observed regio- and stereoselectivities.

Spiro-dihydrobenzo-silole diphenol compounds, synthesis method and application thereof (by machine translation)

The invention discloses a spirodiclole diphenol compound as shown in a formula I as well as a synthesis method and application thereof. The method has the characteristics of simplicity and convenience in operation, easily available raw materials, mild rea