77721-48-3

Basic information

• Product Name: 2-Hydroxi-5-methylphenylazid
• Synonyms: 2-Hydroxi-5-methylphenylazid
• CAS NO: 77721-48-3
• Molecular Weight: 149.152
• Mol File: 77721-48-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Hydroxi-5-methylphenylazid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hydroxi-5-methylphenylazid(77721-48-3)
• EPA Substance Registry System: 2-Hydroxi-5-methylphenylazid(77721-48-3)

Safety Data

• Hazardous Substances Data: 77721-48-3(Hazardous Substances Data)

Upstream product

• 106-44-5 p-cresol 
• 852569-85-8 4-dichloroacetoxy-4-methyl-2,5-cyclohexadienone 
• 87842-95-3 2-Diazo-4-methylphenol 

Downstream Products

• 65244-49-7 C₁₄H₁₅N₃O 
• 95-84-1 3-amino-4-hydroxytoluene 
• 65245-89-8 C₁₄H₁₅N₅O 

Relevant articles and documents

Direct Azidation of Phenols

Direct azidation of phenols was developed. By treating chloroimidazolinium chloride 1b and sodium azide with phenol in the presence of a secondary amine in methoxyethanol, ortho-azidation of phenol was achieved.

ELECTROPHILIC AZIDIZING AGENT OR DIAZOTIZING AGENT

PROBLEM TO BE SOLVED: To provide a novel electrophilic azidizing agent that is safe without explosibility, capable of azidizing a nucleophilic compound in an electrophilic manner. SOLUTION: The present invention provides an azide imidazolium derivative re