77740-05-7

Basic information

• Product Name: Benzenecarboximidamide, N-[1,1'-biphenyl]-2-yl-
• CAS NO: 77740-05-7
• Molecular Formula: C19H16N2
• Molecular Weight: 272.349
• Mol File: 77740-05-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenecarboximidamide, N-[1,1'-biphenyl]-2-yl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidamide, N-[1,1'-biphenyl]-2-yl-(77740-05-7)
• EPA Substance Registry System: Benzenecarboximidamide, N-[1,1'-biphenyl]-2-yl-(77740-05-7)

Safety Data

• Hazardous Substances Data: 77740-05-7(Hazardous Substances Data)

Upstream product

• 90-41-5 2-phenylaniline 
• 100-47-0 benzonitrile 

Downstream Products

• 89069-72-7 3-(2-biphenyl)-2-phenyl-4(3H)-pyrimidinone 
• 89069-89-6 3-(2-biphenyl)-2,6-diphenyl-4(3H)-pyrimidinone 
• 52648-48-3 N-(phenylmethyl)-(1,1'-biphenyl)-2-amine 
• 55-21-0 benzamide 
• 2720-93-6 6-phenylphenanthridine 

Relevant articles and documents

Base-Mediated Amination of Alcohols Using Amidines

Novel and efficient base-mediated N-alkylation and amidation of amidines with alcohols have been developed, which can be carried out in one-pot reaction conditions, which allows for the synthesis of a wide range of N-alkyl amines and free amides in good to excellent yields with high atom economy. In contrast to borrowing hydrogen/hydrogen autotransfer or oxidative-type N-alkylation reactions, in which alcohols are activated by transition-metal-catalyzed or oxidative aerobic dehydrogenation, the use of amidines provides an effective surrogate of amines. This circumvents the inherent necessity in N-alkylation of an oxidant or a catalyst to be stabilized by ligands.