77745-97-2

Basic information

• Product Name: 10-acetyl-cis-bicyclo<7.1.0>decane tosylhydrazone
• Synonyms: 10-acetyl-cis-bicyclo<7.1.0>decane tosylhydrazone
• CAS NO: 77745-97-2
• Molecular Weight: 348.51
• Mol File: 77745-97-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 10-acetyl-cis-bicyclo<7.1.0>decane tosylhydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: 10-acetyl-cis-bicyclo<7.1.0>decane tosylhydrazone(77745-97-2)
• EPA Substance Registry System: 10-acetyl-cis-bicyclo<7.1.0>decane tosylhydrazone(77745-97-2)

Safety Data

• Hazardous Substances Data: 77745-97-2(Hazardous Substances Data)

Upstream product

• 77745-95-0 10-acetyl-cis-bicyclo<7.1.0>decane 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 3726-88-3 (Z,Z)-1,3-cyclononadiene 
• 77745-94-9 cis-bicyclo<7.1.0>decane-10-carboxylic acid 
• 77745-98-3 ethyl cis-bicyclo<7.1.0>dec-2-ene-2-carboxylate 
• 77745-93-8 (1R,9S)-Bicyclo[7.1.0]decane-10-carboxylic acid ethyl ester 
• 77746-01-1 cis-bicyclo<7.1.0>dec-2-ene-10-carboxaldehyde tosylhydrazone 
• 77746-00-0 cis-bicyclo<7.1.0>dec-2-ene-10-carboxaldehyde 

Relevant articles and documents

Thermal valence isomerization of cis-fused bicyclic cyclobutenes. A study of orbital symmetry control

This study shows that thermally promoted valence isomerizations of cis-fused bicyclic cyclobutenes, when free of steric constraint, yield products arising from both orbital symmetry allowed conrotatory openings of the labile σ bond in the cyclobutene ring. In the case of the related vinylcyclobutenes, one conrotatory mode produces a stable cis,trans,cis monocyclic triene whereas fission in the other allowed sense affords a thermally labile trans,cis,cis monocyclic triene which, in turn, cyclizes to yield a cyclohexadiene derivative. The product distributions are evaluated in terms of secondary orbital interactions.