77896-89-0Relevant articles and documents
ACYCLIC STEREOCONTROL IN THE ADDITION OF γ-ALKYLTHIO-ALLYLBORONATES TO ALDEHYDES
Hoffmann, Reinhard W.,Kemper, Bruno
, p. 2219 - 2224 (2007/10/02)
The Z-isomer 10 of the γ-alkylthio-allylboronates adds to aldehydes giving the syn diastereomer 4 of the product homoallyl-alcohol.The E-isomer 12 leads in turn to the anti-diastereomer 5 with a high degree of acyclic stereocontrol.Kinetic diasteroselecti
Diastereoselective addition of γ-alkylthio-allylboronates to aldehydes
Hoffmann, Reinhard W.,Kemper, Bruno
, p. 4883 - 4886 (2007/10/02)
The Z- and E-γ-alkylthio-allylboronates 5 and 10 were found to add aldehydes forming diastereoselectively the adducts 7 and 6 respectively in high yield.