77922-78-2Relevant articles and documents
Unequivocal proof of slowed chromium tricarbonyl rotation in a sterically crowded arene complex: An X-ray crystallographic and variable-temperature high-field NMR study of (C6Et5COCH3)Cr(CO)3
Downton,Mailvaganam,Frampton,Sayer,McGl inchey
, p. 27 - 32 (1990)
The low-temperature 13C NMR spectrum of (C6Et5COCH3) Cr(CO)3 is explicable only in terms of a single sterioisomer, i.e., the 1-proximal-acetyl-2,4,6-distal-3,5-p roximal conformer. The Cr(CO)3/s
Charge-transfer probes for molecular recognition via steric hindrance in donor-acceptor pairs
Rathore,Lindeman,Kochi
, p. 9393 - 9404 (2007/10/03)
Molecular association of various aromatic hydrocarbons (D, including sterically hindered donors) with a representative group of diverse acceptors (A = quinone, trinitrobenzene, tetracyanoethylene, tropylium, tetranitromethane, and nitrosonium) is visually apparent in solution by the spontaneous appearance of distinctive colors. Spectral (UV-vis) analyses of the colored solutions reveal their charge-transfer origin (λ(CT)) and they provide quantitative information of the intermolecular association in the form of the K(DA) and ε(CT) values for the formation and visualization, respectively, of different [D,A] complexes. Importantly, such measurements establish charge-transfer absorption to be a sensitive analytical tool for evaluating the steric inhibition of donor-acceptor association. For example, the steric differences among various hindered aromatic donors in their association with quinone are readily dramatized in their distinctive charge-transfer (color) absorptions and verified by X-ray crystallography of the charge-transfer crystals and/or QUANTA molecular modeling calculations of optimum intermolecular separations allowed by van der Waals contacts.
