779342-75-5

Basic information

• Product Name: NULL
• Synonyms: (E)-tert-Butyl 4-chlorobenzylidenecarbaMate;tert-Butyl 4-chlorobenzylidenecarbamate
• CAS NO: 779342-75-5
• Molecular Formula: C₁₂H₁₄ClNO₂
• Molecular Weight: 239.69806
• EINECS: -0
• Mol File: 779342-75-5.mol
• Article Data: 23

Chemical Properties

• Boiling Point: 312.0±44.0 °C(Predicted)
• Appearance: /
• Density: 1.10±0.1 g/cm3(Predicted)
• Storage Temp.: 2-8°C
• PKA: -0.83±0.50(Predicted)
• CAS DataBase Reference: NULL(CAS DataBase Reference)
• NIST Chemistry Reference: NULL(779342-75-5)
• EPA Substance Registry System: NULL(779342-75-5)

Safety Data

• Hazardous Substances Data: 779342-75-5(Hazardous Substances Data)

Upstream product

• 4248-19-5 tert-butyl carbazate 
• 104-88-1 4-chlorobenzaldehyde 
• 774225-25-1 N-(tert-butoxycarbonyl)-α-(phenylsulfonyl)-4-chlorobenzylamine 
• 365441-81-2 [(4-chloro-phenyl)-(toluene-4-sulfonyl)-methyl]-carbamic acid tert-butyl ester 

Downstream Products

• 1043959-29-0 diethyl (1S)-1-[(R)-(tert-butoxycarbonylamino)(4-chlorophenyl)methyl]-2-oxocyclopentanephosphonate 
• 1078628-61-1 tert-butyl 2-(bis(benzyloxy)phosphoryl)-1-(4-chlorophenyl)-2-nitropropylcarbamate 
• 1078628-65-5 tert-butyl 2-(bis(pentan-3-yloxy)phosphoryl)-1-(4-chlorophenyl)-2-nitropropylcarbamate 
• 1078628-68-8 tert-butyl (1R,2S)-2-(bis(2,4-dimethylpentan-3-yloxy)phosphoryl)-1-(4-chlorophenyl)-2-nitropropylcarbamate 
• 1078628-67-7 tert-butyl (1R,2S)-2-(bis(2,4-dimethylpentan-3-yloxy)phosphoryl)-1-(4-chlorophenyl)-2-nitropropylcarbamate 

Relevant articles and documents

γ-Selective Vinylogous Aza-Morita-Baylis-Hillman Reaction with N -Carbamoylimines

Vinylogous aza-Morita-Baylis-Hillman (aza-MBH) reactions of a vinylcyclopentenone with N -Boc imines provide the corresponding γ-adducts in high regioselectivity (10 examples). While the corresponding reactions with N -Ts imines give the α-adducts and γ-a

Enantioselective Construction of Sulfur-Containing Tetrasubstituted Stereocenters via Asymmetric Functionalizations of α-Sulfanyl Cyclic Ketones

Asymmetric functionalizations of α-sulfanyl cyclic ketones were realized via chiral phosphoric acid catalyzed enantioselective addition reactions with aldimines, azodicarboxylates and allenamides. A series of chiral organosulfur compounds possessing sulfur-containing tetrasubstituted stereocenters were accessed via these methods, with excellent regioselectivities and high stereoselectivities. (Figure presented.).

Two Distinct Ag(I)- And Au(I)-Catalyzed Olefinations between α-Diazo Esters and N-Boc-Derived Imines

Metal-catalyzed reactions between α-diazo esters and imines were well-known to yield aziridine derivatives exclusively. This work reports two new olefination reactions between N-Boc-derived (Boc = tert-Butyloxycarbonyl) imines and α-diazo esters with Ag(I) and Au(I) catalysts, respectively. Our mechanistic studies reveal that these new olefinations involve an initial attack of diazo esters on metal/imine complexes to form Mannich-addition intermediates, which subsequently afford α-aryl-β-aminoacrylates via a Roskamp reaction, or to form β-aryl-β-aminoacrylates via the formation of silver carbenes.