78008-09-0Relevant articles and documents
Synthesis of 2(R),3-dihydroxypropyl and 2(R),3(R)-dihydroxybutyl β-d-fructopyranosides and some derivatives
Sung'hwa, Fortunatus,Strik, Axel,Regeling, Henk,Zwanenburg, Binne,Chittenden, Gordon J.F.
, p. 846 - 854 (2006)
The synthesis of 2(R),3-dihydroxypropyl and 2(R),3(R)-dihydroxybutyl β-d-fructopyranosides, and some derivatives, employing Sharpless-type catalytic asymmetric dihydroxylation procedures is described. Some aspects of the reactions, including stereoselecti
Reaction of D-fructose, D-glucose and inulin with alcohols in the presence of iodine; a novel glycosidation procedure
Verhart, Cor G.J.,Fransen, Carel T.M.,Zwanenburg, Binne,Chittenden, Gordon J.F.
, p. 133 - 139 (2007/10/03)
An efficient procedure for the glycosidation of D-fructose and D-glucose catalyzed by iodine is described. The reaction yields mainly alkyl glycofuranosides. Treatment of inulin under similar conditions leads to inter-glycosidic bond cleavage and to formation of alkyl D-fructofuranosides. The reaction conditions are particularly mild and relatively selective.
Preparation and catalytic hydrogenolysis of some ω-halogenoalkyl β-D-fructopyranosides; a convenient route to simple alkyl β-D-fructopyranosides
Raaijmakers, Harry W. C.,Eveleens, Susan M.,Arnouts, Esther G.,Zwanenburg, Binne,Chittenden, Gordon J. F.
, p. 511 - 514 (2007/10/02)
The acid-catalysed reactions of D-fructose, sucrose and inulin with ω-halogenoalkyl alcohols yield the corresponding β-D-fructopyranosides.Catalytic hydrogenolysis of these glycosides provides a simple route to some crystalline alkyl β-D-fructopyranosides of potential biological interest.