78038-79-6

Basic information

• Product Name: (+/-)-2,2'-bis(hydroxymethyl)-1,1'-binaphthyl
• Synonyms: (+/-)-2,2'-bis(hydroxymethyl)-1,1'-binaphthyl
• CAS NO: 78038-79-6
• Molecular Weight: 314.384
• Mol File: 78038-79-6.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: (+/-)-2,2'-bis(hydroxymethyl)-1,1'-binaphthyl(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-2,2'-bis(hydroxymethyl)-1,1'-binaphthyl(78038-79-6)
• EPA Substance Registry System: (+/-)-2,2'-bis(hydroxymethyl)-1,1'-binaphthyl(78038-79-6)

Safety Data

• Hazardous Substances Data: 78038-79-6(Hazardous Substances Data)

Upstream product

• 76373-12-1 l-menthyl 1-bromo-2-naphthoate 
• 77196-14-6 (SS)-tetranaphtho<2,1-b:1,2-d:1,2-h:1,2-j><1,6>dioxacyclododeca-2,4,8,10-tetraene-7,12-dione 
• 77196-14-6 C₄₂H₂₄O₄ 
• 37803-02-4 (S)-2,2'-bis(bromomethyl)-1,1'-binaphthyl 
• 99636-47-2 [1,1']Binaphthalenyl-2,2'-dicarboxylic acid dinaphthalen-2-yl ester 
• 98834-92-5 (S)-2,2'-Bis-1,1'-binaphthyl 
• 18531-96-9 (S)-1,1'-binaphthyl-2,2'-dicarboxylic acid 
• 80684-40-8 [1,1']Binaphthalenyl-2,2'-dicarboxylic acid bis-[2'-(naphthalene-2-carbonyloxy)-[1,1']binaphthalenyl-2-yl] ester 
• 76373-14-3 1-Bromo-naphthalene-2-carboxylic acid 1-phenyl-ethyl ester 
• 76373-14-3 1-Bromo-naphthalene-2-carboxylic acid 1-phenyl-ethyl ester 
• 76373-13-2 1-Bromo-naphthalene-2-carboxylic acid (3S,8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester 
• 76373-16-5 1-Bromo-naphthalene-2-carboxylic acid 1-methyl-heptyl ester 

Downstream Products

• 3594-94-3 (S)-2,2'-Bis-1,1'-binaphthyl 
• 19634-89-0 (R)-2,2'-dimethyl-1,1'-binaphthyl 
• 18531-96-9 (S)-1,1'-binaphthyl-2,2'-dicarboxylic acid 
• 746-46-3 (R)-1,1'-binaphthyl-2,2'-dicarboxylic acid 
• 60536-98-3 2,2'-dimethyl-1,1'-binaphthyl 

Relevant articles and documents

Solution-phase synthesis and evaluation of tetraproline chiral stationary phases

A protocol was developed for the solution-phase synthesis of multigram amounts of two 9-fluorenylmethoxycarbonyl (Fmoc)-protected tetraproline peptides. These tetraproline peptides were then attached to amino derivatized silica gel. The replacement of the Fmoc group with the trimethylacetyl group lead to two tetraproline chiral stationary phases (CSPs). A comparison of the chromatographic behavior of these two solution-phase-synthesized tetraproline CSPs with that prepared by stepwise solid-phase synthesis revealed that all three had similar chromatographic performance for resolving 53 model analytes. This suggests that the solution-phase synthesis of oligoprolines, which allows for the specific benefits of good batch reproducibility, selector homogeneity, and possibly low cost, is a feasible alternative to the solid-phase synthesis of oligoproline CSPs. Copyright

Reductive ring opening of dihydrodibenzothiepine and dihydrodinaphtho- oxepine and -thiepine

The 4,4′di-tert-butylbiphenyl (DTBB)-catalysed lithiation of dihydrodibenzothiepine (1) at -78°C for 30 min followed by reaction with a carbonyl compound [tBuCHO, Ph(CH2)2CHO, PhCHO, (n-C5H11)2/

C2 Symmetric Amines. II. Asymmetric Synthesis of C2 (3S,3'S)-and (3R,3'R)Dimethyl 4H-DinaphthAzepines

The C2-symmetric dimethyl amines (1a, 1b) were prepared in high stereoselectivity by carbanion alkylation of their respective formamidines.