78136-55-7

Basic information

• Product Name: 4-BENZYLOXY-3-METHOXY-TOLUENE
• Synonyms: 4-BENZYLOXY-3-METHOXY-TOLUENE;2-Methoxy-4-Methyl-1-(phenylMethoxy)benzene
• CAS NO: 78136-55-7
• Molecular Formula: C₁₅H₁₆O₂
• Molecular Weight: 228.29
• Product Categories: Aromatics Compounds;Aromatics
• Mol File: 78136-55-7.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• Solubility: Ethanol, Methanol
• CAS DataBase Reference: 4-BENZYLOXY-3-METHOXY-TOLUENE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BENZYLOXY-3-METHOXY-TOLUENE(78136-55-7)
• EPA Substance Registry System: 4-BENZYLOXY-3-METHOXY-TOLUENE(78136-55-7)

Safety Data

• Hazardous Substances Data: 78136-55-7(Hazardous Substances Data)

Usage

Chemical Properties

Yellow Crystalline Solid

Upstream product

• 93-51-6 2-Methoxy-4-methylphenol 
• 100-44-7 benzyl chloride 
• 2426-87-1 3-methoxy-4-(phenylmethoxy)benzaldehyde 
• 100-39-0 benzyl bromide 
• 1373139-20-8 C₁₇H₁₈O₅ 
• 140-88-5 ethyl acrylate 
• 57371-42-3 4-allyl-1-benzyloxy-2-methoxybenzene 
• 33693-48-0 4-benzyloxy-3-methoxybenzyl alcohol 

Downstream Products

• 121086-26-8 1-benzyloxy-2-methoxy-4-methyl-5-nitrobenzene 
• 131792-48-8 (RS)-10-(benzyloxy)-9-methoxyaporphine hydrochloride 
• 131792-47-7 (RS)-1-<2-amino-4-(benzyloxy)-5-methoxybenzyl>-2-methyl-1,2,3,4-tetrahydroisoquinoline dihydrochloride 
• 387881-00-7 1-(benzyloxy)-5-bromo-2-methoxy-4-methylbenzene 
• 883846-97-7 5-(benzyloxy)-4-methoxy-2-methylbenzoic acid 
• 1360546-62-8 methyl 5-(benzyloxy)-4-methoxy-2-methylbenzoate 
• 883840-51-5 methyl 5-acetoxy-4-methoxy-2-methylbenzoate 
• 1360546-64-0 methyl 5-acetoxy-3-bromo-4-methoxy-2-methylbenzoate 
• 131236-68-5 methyl 5-hydroxy-4-methoxy-2-methylbenzene-1-carboxylate 
• 128533-02-8 sauristolactam 
• 97400-62-9 5-(benzyloxy)-4-methoxy-2-methylbenzaldehyde 

Relevant articles and documents

IRAK DEGRADERS AND USES THEREOF

The present invention provides compounds, compositions thereof, and methods of using the same.

An unprecedented deoxygenation protocol of benzylic alcohols using bis(1-benzotriazolyl)methanethione

A facile and regioselective two-step protocol for the deoxygenation of benzylic alcohols using bis(benzotriazole)methanethione has been devised. Benzotriazole derivatives, namely, benzyloxythioacylbenzotriazoles (ROCSBt), on reaction with silanes or Bu3SnH under microwave irradiation or conventional heating undergo a free radical β-scission of C-O bond instead of N-N bond (benzotriazole ring cleavage) to afford a deoxy product. The methodology has various applications because it selectively deoxygenates benzylic alcohols with the aid of a relatively nontoxic (TMS)3SiH reagent as an acceptable alternate to Bu3SnH.

An efficient and practical total synthesis of sauristolactam

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