78185-31-6

Basic information

• Product Name: (2R,3S,4S)-2,3-trans-3,4-cis-3,3',4',7-tetrahydroxy-4-<(2S,3S)-2,3-trans-3,3',4',7-tetrahydroxyflavan-6-yl>flavan
• CAS NO: 78185-31-6
• Molecular Weight: 546.53
• Mol File: 78185-31-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2R,3S,4S)-2,3-trans-3,4-cis-3,3',4',7-tetrahydroxy-4-<(2S,3S)-2,3-trans-3,3',4',7-tetrahydroxyflavan-6-yl>flavan(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,4S)-2,3-trans-3,4-cis-3,3',4',7-tetrahydroxy-4-<(2S,3S)-2,3-trans-3,3',4',7-tetrahydroxyflavan-6-yl>flavan(78185-31-6)
• EPA Substance Registry System: (2R,3S,4S)-2,3-trans-3,4-cis-3,3',4',7-tetrahydroxy-4-<(2S,3S)-2,3-trans-3,3',4',7-tetrahydroxyflavan-6-yl>flavan(78185-31-6)

Safety Data

• Hazardous Substances Data: 78185-31-6(Hazardous Substances Data)

Upstream product

• 895-23-8 (+)<(2S,3S)-2,3-cis-flavan-3,3',4',7-tetraol> 
• 967-27-1 (+)-mollisacacidin 
• 78139-48-7 (2R,3S,4S)-2,3-trans-3,4-cis-3,3',4',7-tetrahydroxy-4-<(2R,3S)-2,3-trans-3,3',4',7-tetrahydroxyflavan-6-yl>flavan 
• 490-49-3 fisetinidol 

Downstream Products

• 127644-51-3 (2S,3S,4R,7S,8R)-2,8-Bis-(3,4-dihydroxy-phenyl)-4-(2,4-dihydroxy-phenyl)-3,4,7,8-tetrahydro-2H,6H-pyrano[3,2-g]chromene-3,7-diol 
• 127644-53-5 (2S,3S,4R,7S,8S)-2,8-Bis-(3,4-dihydroxy-phenyl)-4-(2,4-dihydroxy-phenyl)-3,4,7,8-tetrahydro-2H,6H-pyrano[3,2-g]chromene-3,7-diol 
• 127644-49-9 (2R,3S,4R,7S,8S)-2,8-Bis-(3,4-dihydroxy-phenyl)-4-(2,4-dihydroxy-phenyl)-3,4,7,8-tetrahydro-2H,6H-pyrano[3,2-g]chromene-3,7-diol 
• 127644-47-7 (2R,3S,4R,7S,8R)-2,8-Bis-(3,4-dihydroxy-phenyl)-4-(2,4-dihydroxy-phenyl)-3,4,7,8-tetrahydro-2H,6H-pyrano[3,2-g]chromene-3,7-diol 
• 127644-39-7 (+)-epifisetinidol-(4β,6)-(-)-fisetinidol 
• 127644-41-1 (4β,6)-bis-(+)-epifisetinidol 

Relevant articles and documents

Oligomeric Flavanoids. Part 10. Structure and Synthesis of the First Tetrahydropyranochromenes Related to (4,6)-Bis-(-)-fisetinidol Profisetinidins

The range of natural bis-fisetinidol profisetinidins is extended by identification of (+)-epifisetinidol-(4α,6)-(-)-fisetinidol (5), (4α,6)-bis-(+)-epifisetinidol (7), (4β,6')-bis-(-)-fisetinidol (13), and (-)-fisetinidol-(4β,6')-(+)-epifisetinidol (15).They are accompanied in the heartwood of Colophospermum mopane by the first tetrahydropyranochromenes (17), (19), (21), and (23), related to the (4,6)-bis-(-)-fisetinidol profisetinidins (1) and (2).Under mild basic conditions the latter compounds undergo pyran rearrangements affording tetrahydropyranochromenes (17), (19), (21), and (23) as well as two additional C-2(F) epimeric pairs (25), (27), and (29), (31).The same intermediate quinone-methide presumably leading to the c-ring-isomerized analogues may feasibly also explain the genesis of the variety of compounds in the mopane displaying a C-2-epimeric relationship to the predominant (-)-fisetinidol monomeric precursor.