783-08-4

Basic information

• Product Name: N-BENZYLIDENE-P-METHOXYANILINE
• Synonyms: benzylidene-(4-methoxyphenyl)amine;N-(4-methoxyphenyl)-1-phenylmethanimine;N-(4-methoxyphenyl)-1-phenyl-methanimine;N-BENZYLIDENE-P-METHOXYANILINE;4-Methoxy-N-(phenylmethylene)benzenamine;N-(p-Methoxyphenyl)benzenemethanimine;N-Benzylidene-4-methoxyaniline;N-Benzylidene-p-anisylamine
• CAS NO: 783-08-4
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.25912
• Mol File: 783-08-4.mol
• Article Data: 262

Chemical Properties

• Boiling Point: 354.3 °C at 760 mmHg
• Flash Point: 136.7 °C
• Appearance: /
• Density: 0.99 g/cm³
• Vapor Pressure: 6.92E-05mmHg at 25°C
• Refractive Index: 1.539
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: N-BENZYLIDENE-P-METHOXYANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: N-BENZYLIDENE-P-METHOXYANILINE(783-08-4)
• EPA Substance Registry System: N-BENZYLIDENE-P-METHOXYANILINE(783-08-4)

Safety Data

• Hazardous Substances Data: 783-08-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H13NO/c1-16-14-9-7-13(8-10-14)15-11-12-5-3-2-4-6-12/h2-11H,1H3/b15-11+

Upstream product

• 100-52-7 benzaldehyde 
• 104-94-9 4-methoxy-aniline 
• 588-53-4 4-benzylidenamino-phenol 
• 77-78-1 dimethyl sulfate 
• 74-88-4 methyl iodide 
• 19064-76-7 N-benzylidene-4-methoxyaniline oxide 
• 17377-95-6 benzyl(4-methoxyphenyl)amine 
• 2211-66-7 N-phenyl(methylidene)cyclohexanamine 
• 110788-30-2 C₂₅H₂₂AsNO 
• 123-11-5 4-methoxy-benzaldehyde 
• 62-53-3 aniline 
• 57527-55-6 (E)-N-benzylidenebutan-1-amine 
• 27845-53-0 (E)-N-cyclohexyl-1-phenylmethanimine 
• 101960-60-5 [(Z)-4-Methoxy-phenylimino]-phenyl-acetic acid 

Downstream Products

• 24870-10-8 maleic acid mono(4-methoxyphenyl)amide 
• 56264-82-5 acetoxy-(N-acetyl-p-anisidino)-phenyl-methane 
• 420133-77-3 2,3,6-trichloro-4-methoxy-aniline 
• 60566-20-3 N-(4-methoxyphenyl)-N'-(4-methoxyphenyl)benzamidine 
• 100-52-7 benzaldehyde 
• 51527-45-8 (±)-trans-1-(4-methoxyphenyl)-3,4-diphenylazetidin-2-one 
• 6709-42-8 N-(4-methoxyphenyl)-1,1-diphenylmethylamine 
• 32795-58-7 2-phenyl-6-methoxyquinoline-4-carboxylic acid 
• 116028-06-9 1-(4-methoxy-phenyl)-3,3,4-triphenyl-azetidin-2-one 
• 17377-95-6 benzyl(4-methoxyphenyl)amine 
• 6725-34-4 thiobenzaldehyde 
• 98861-13-3 8-methoxy-9b-methyl-4-phenyl-2,3,3a,4,5,9b-hexahydro-furo[3,2-c]quinoline 
• 34798-63-5 3-(4-methoxy-phenyl)-5-naphthalen-2-yloxymethyl-2-phenyl-oxazolidine 
• 34798-59-9 3-(4-methoxy-phenyl)-5-phenoxymethyl-2-phenyl-oxazolidine 

Relevant articles and documents

Controlling Proton-Coupled Electron Transfer in Bioinspired Artificial Photosynthetic Relays

Bioinspired constructs consisting of benzimidazole-phenol moieties bearing N-phenylimines as proton-accepting substituents have been designed to mimic the H-bond network associated with the TyrZ-His190 redox relay in photosystem II. These compo

Method for preparing asymmetric imine or asymmetric secondary amine compound through photocatalysis

The invention relates to a method for preparing asymmetric imine or asymmetric secondary amine compounds through photocatalysis. According to the method, under the conditions of illumination and inert gas, different types of photocatalysts supported by cocatalysts are selected, so that an aromatic alcohol compound and an aromatic amino compound can react to obtain the asymmetric imine compound or the asymmetric secondary amine compound. The method can be used for replacing the existing mature organic synthesis process, is mild in condition and high in selectivity, has universality and is suitable for industrial production.

Redox-Neutral Imination of Alcohol with Azide: A Sustainable Alternative to the Staudinger/Aza-Wittig Reaction

The traditional Staudinger/aza-Wittig reaction represents one of the most powerful tools for imine formation. However, for this multistep procedure, the sacrificial phosphine has to be used, resulting in difficulties in the purification process and waste disposal at the same time. Here, we report a redox-neutral azide-alcohol imination methodology enabled by a base-metal nickel PN3 pincer catalyst. The one-step, waste-free, and high atom-economical features highlight its advantages further. Moreover, mechanistic insight suggests a non-metal-ligand cooperation pathway based on the observation of an intermediate and density functional theory calculations.