78465-53-9

Basic information

• Product Name: (1S)-1,5-anhydro-2-deoxy-1-(2,4-dimethoxyphenyl)-3,4,6-tris-O-acetyl-D-erythro-hex-2-enitol
• Synonyms: (1S)-1,5-anhydro-2-deoxy-1-(2,4-dimethoxyphenyl)-3,4,6-tris-O-acetyl-D-erythro-hex-2-enitol
• CAS NO: 78465-53-9
• Molecular Weight: 408.405
• Mol File: 78465-53-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1S)-1,5-anhydro-2-deoxy-1-(2,4-dimethoxyphenyl)-3,4,6-tris-O-acetyl-D-erythro-hex-2-enitol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S)-1,5-anhydro-2-deoxy-1-(2,4-dimethoxyphenyl)-3,4,6-tris-O-acetyl-D-erythro-hex-2-enitol(78465-53-9)
• EPA Substance Registry System: (1S)-1,5-anhydro-2-deoxy-1-(2,4-dimethoxyphenyl)-3,4,6-tris-O-acetyl-D-erythro-hex-2-enitol(78465-53-9)

Safety Data

• Hazardous Substances Data: 78465-53-9(Hazardous Substances Data)

Upstream product

• 91-52-1 2,4 dimethoxybenzoic acid 
• 2873-29-2 D-glucal triacetate 
• 151-10-0 1,3-Dimethoxybenzene 
• 2873-29-2 3,4,6-triacetyl-D-galactal 

Downstream Products

• 78465-57-3 Acetic acid (2R,3S,6S)-2-acetoxymethyl-6-(2,4-dimethoxy-phenyl)-4-[(E)-hydroxyimino]-tetrahydro-pyran-3-yl ester 

Relevant articles and documents

Regio- and stereoselective synthesis of 2-deoxy-C-aryl glycosides via palladium catalyzed decarboxylative reactions

An efficient and versatile approach for the synthesis of 2-deoxy-C-aryl glycosides is reported. This strategy is based on a palladium-catalyzed decarboxylative Heck coupling reaction of benzoic acids and glycals. A wide variety of glycals and benzoic acid

NOUVELLE VOIE D'ACCES AUX C-GLYCOSIDES.

Palladium salt catalysed arylation of 3,4,6-triacetyl-D-glucal and 3,4,6-triacetyl-D-galactal is described.This reaction provides a new acces to 2'-deoxy-C-nucleosides precursors.